摘要
报道了6个新的含均同或混合茂铁阳离子和[M(dmit)_2]阴离子的金属有机自由基离子盐类化合物[Fe(CpMe)_2]IM(dmit)_2]和[FeCp(Tol)],[M(dmit)_2]的合成和鉴定,测定了化合物的电导率,讨论了化合物的结构对电导率的影响,发现[Fe(CpMe)_2][M(dmit)_2]的室温电导率比相应的[M(mnt)_2]阴离子盐要高3～7个数量级.
Six new organometallic radical ionic salts,[Fe(CpMe)2][M(dmit)2] and [FeCp(Tol)]n[M(dmit)2]n(M=Ni,Pd,Pt,Cu or Co;CpMe=methylcyclopentadienyl;Tol=toluene;H2dmit=4,5-dimercapto-1,3-dithiole-2-thione;n=1 or 2)were synthesized,and characterized by elemental analysis,infrared and mass spectroscopy.The electrical conductivity of solid state was reported and discussed in terms of structure-property relationship.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1992年第11期1398-1400,共3页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
关键词
自由基离子盐
电导性
金属有机盐
Organometailic compounds,Radical ionic salts,Dmit,Synthesis,Conductivity
