Steel slag contains a large amount of calcium silicate,which can react with CO_(2)to generate CaCO_(3)and SiO_(2)colloid,thus steel slag may become a cementitious material with a certain strength.High strength porous ...Steel slag contains a large amount of calcium silicate,which can react with CO_(2)to generate CaCO_(3)and SiO_(2)colloid,thus steel slag may become a cementitious material with a certain strength.High strength porous steel slag carbonated brick was prepared by adding easily decomposed bicarbonate solid into steel slag as pore-forming agent and then accelerating carbonation.A variety of characterization methods were used to characterize the composition and micro-structure of the samples.The effects of different pore-forming agent dosage and carbonation time on the properties of pore steel slag blocks were discussed.The results show that the addition of ammonia bicarbonate promotes the nucleation and growth of columnar calcite.The strength of steel slag block mixed with 30%pore forming agent can reach 24.8 MPa after 1 day of carbonation,and then the strength development tends to slow down.展开更多
The article analyzed the main groups of thermal insulation(TIM)and slag-forming(SFM)mixtures produced by leading foreign companies:acidic ones based on the SiO2–Al2O3 system,basic ones based on the CaO–MgO–Al2O3 sy...The article analyzed the main groups of thermal insulation(TIM)and slag-forming(SFM)mixtures produced by leading foreign companies:acidic ones based on the SiO2–Al2O3 system,basic ones based on the CaO–MgO–Al2O3 system and medium basic ones based on the CaO(MgO)system–Al2O3–SiO2.It is shown that achieving the necessary properties of the SFM and TIM requires strict observance of the mass content of the components of mixtures produced on the basis of synthetic materials in granular form with a given dispersion.Compliance with a given composition and dispersion is associated with the need to provide a given melting temperature(for intermediate ladles 1250–1450℃,for molds 950–1150℃),neutrality to the cast metal,protection of the melt from secondary oxidation,minimization of heat loss from the melt mirror,absorption of non-metallic inclusions of various natures(Al2O3,CaO,SiO2,TiO2,less often MgO-containing)and sizes;as well as a number of specific requirements:compatibility with the working layer of the lining of the bucket,maintaining the work of the stoppers,minimizing harmful gaseous emissions,etc.It is known that Al2O3,TixOy,and CaO refractory inclusions in steel cause the majority of defects on the surface of a cold-rolled sheet,therefore,the aim of the work was to analyze the physicochemical regularities and melting paths of the wollastonite-containing compositions during the assimilation of nonmetallic inclusions by them.To analyze the melting paths of the wollastonite-containing compositions in the CaO–Al2O3–SiO2 system,a diagram of the primary crystallization field of anorthite and the adjacent boundary curves is shown,indicating the directions of temperature drop and designating invariant points.The presented scheme adequately reflects the topological regularities of the state diagram of the CaO–Al2O3–SiO2 system.To analyze the melting paths of the wollastonite-containing SFM compositions during the assimilation of TiOx impurities from steel melts,a diagram of the primary crystalliz展开更多
基金the National Natural Science Foundation of China(No.51925205)Hubei Technology Innovation Key Program(No.2018AAA004)。
文摘Steel slag contains a large amount of calcium silicate,which can react with CO_(2)to generate CaCO_(3)and SiO_(2)colloid,thus steel slag may become a cementitious material with a certain strength.High strength porous steel slag carbonated brick was prepared by adding easily decomposed bicarbonate solid into steel slag as pore-forming agent and then accelerating carbonation.A variety of characterization methods were used to characterize the composition and micro-structure of the samples.The effects of different pore-forming agent dosage and carbonation time on the properties of pore steel slag blocks were discussed.The results show that the addition of ammonia bicarbonate promotes the nucleation and growth of columnar calcite.The strength of steel slag block mixed with 30%pore forming agent can reach 24.8 MPa after 1 day of carbonation,and then the strength development tends to slow down.
文摘The article analyzed the main groups of thermal insulation(TIM)and slag-forming(SFM)mixtures produced by leading foreign companies:acidic ones based on the SiO2–Al2O3 system,basic ones based on the CaO–MgO–Al2O3 system and medium basic ones based on the CaO(MgO)system–Al2O3–SiO2.It is shown that achieving the necessary properties of the SFM and TIM requires strict observance of the mass content of the components of mixtures produced on the basis of synthetic materials in granular form with a given dispersion.Compliance with a given composition and dispersion is associated with the need to provide a given melting temperature(for intermediate ladles 1250–1450℃,for molds 950–1150℃),neutrality to the cast metal,protection of the melt from secondary oxidation,minimization of heat loss from the melt mirror,absorption of non-metallic inclusions of various natures(Al2O3,CaO,SiO2,TiO2,less often MgO-containing)and sizes;as well as a number of specific requirements:compatibility with the working layer of the lining of the bucket,maintaining the work of the stoppers,minimizing harmful gaseous emissions,etc.It is known that Al2O3,TixOy,and CaO refractory inclusions in steel cause the majority of defects on the surface of a cold-rolled sheet,therefore,the aim of the work was to analyze the physicochemical regularities and melting paths of the wollastonite-containing compositions during the assimilation of nonmetallic inclusions by them.To analyze the melting paths of the wollastonite-containing compositions in the CaO–Al2O3–SiO2 system,a diagram of the primary crystallization field of anorthite and the adjacent boundary curves is shown,indicating the directions of temperature drop and designating invariant points.The presented scheme adequately reflects the topological regularities of the state diagram of the CaO–Al2O3–SiO2 system.To analyze the melting paths of the wollastonite-containing SFM compositions during the assimilation of TiOx impurities from steel melts,a diagram of the primary crystalliz
