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用共振Rayleigh散射光谱研究12-硅钼酸和邻菲罗啉的相互作用

Study on the interaction of 12-silicomolybdic acid with phenanthroline by resonance rayleigh scattering
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摘要 在醋酸钠-盐酸缓冲溶液体系中,邻菲罗啉与12-硅钼酸结合能导致共振瑞利(Rayleigh)散射(RRS)的显著增强,其最大散射波长位于382.8nm处。实验考察了体系的光谱特点、影响因素及最佳条件。该方法呈现出的高灵敏性使邻菲罗啉的检测限达到0.077μg·mL-1。同时还考察了散射增强的原因,吸收光谱和RRS光谱的关系。提出了一种简单、灵敏、快速检测邻菲罗啉的新方法。 In a CH3COONa—HCl buffer solution,a combination of phenanthroline(Phen)with 12-silicomolybdic acid(SM)can result in a significant enhancement of the resonance Rayleigh scattering and the maximum scattering wavelengthsλappear at 382.8nm.The characteristics of RRS spectra of Phen-SM complex,the influencing factors,and the optimum condition of the system have been investigated.The methods exhibit high sensitivities,and the detection limits for Phen is 0.077μg·mL-1.In addition,the enhancement reasons of RRS and the relationship between RRS spectra characteristics of the Phen-SM complex and its absorption spectra have been primarily discussed.A simple,sensitive and fast method for the direct determination of trace amounts of Phen on the basis of RRS has been advanced.
出处 《精细与专用化学品》 CAS 2014年第7期36-40,共5页 Fine and Specialty Chemicals
关键词 共振Rayleigh散射 邻菲罗啉 12-硅钼酸 resonance rayleigh scattering phenanthroline 12-silicomolybdic acid
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