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全固态锂离子选择性电极研究 被引量:3

STUDY ON ALL-SOLID STATE LITHIUM ION SELECTIVE ELECTRODES
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摘要 研究了新型载体HPMBP TOPO体系几种全固态锂离子选择性电极 (涂丝电极、单层全固态电极、聚吡咯修饰层内接触电极 )的性能。与传统型电极相比 ,固态电极响应斜率有所降低 ,而选择性稍有提高。其中聚吡咯修饰层内接触电极性能为最佳 ,该电极响应斜率为 5 6 .7mV/decade ,并具有良好再现性和长期稳定性。 Several solid state lithium ion selective electrodes with new type carriers (coated wire electrode CWE, single piece solid state electrode SPE, solid contact ion selective electrode SCISE) were studied in the paper. The slope values of solid state electrodes were found to be lower than that of the conventional electrode. But the selectivity was improved. The best one was SCISE modified with poly pyrrole. The electrode was of good reproducibility and long term stability with a slope of 56.7mV/decade.
出处 《理化检验(化学分册)》 CAS CSCD 北大核心 2002年第11期568-570,共3页 Physical Testing and Chemical Analysis(Part B:Chemical Analysis)
关键词 全固态锂离子选择性电极 电极响应斜率 性能 HPMBP-TOPO体系 Lithium Solid state ion Selective electrode
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