摘要
用循环伏安法(CV)制备了聚吡咯亚硝酸根离子选择性电极。表征了电极的电化学性能。在1.0x10-1~5.0x10-5mol/L浓度范围内,电极电位与亚硝酸根离子浓度成良好的线性关系,Nernst响应科率为51mv/PNO2-。观察了NO2-在PPy膜中掺杂=去掺杂过程,从而验证了电极响应是基于掺杂机理。
In this paper, NO2- PPy ion selective electrode is prepared by cyclic voltammograms,and the properties of this polypyrrole modified electrode are characterized. There's a good linear relationship between electrode potential and the concentration of NO2- within 10-1 mol/L and 5 x 10-5 mol/L. The mingling process of NO2 - on PPy film is observed on line, and the mingling machanism of the modified electrode studied.
出处
《东莞理工学院学报》
1997年第2期15-18,共4页
Journal of Dongguan University of Technology