摘要
评价绿色催化合成方法的主要标准包括催化剂、试剂或溶剂、反应条件和后处理等。随着绿色化学的不断发展,水相催化或无溶剂合成表现出明显的优势,在催化双吲哚基甲烷衍生物的合成方面更是受到广泛的关注。但是目前尚无针对吲哚基甲烷催化反应过程以及是否使用试剂或溶剂等相关问题的综述报道。因此,对近十年来水相或无溶剂催化合成吲哚基甲烷的反应方法进行了综述,其目的是为指导和设计更为绿色、洁净的合成吲哚基甲烷新方法和思路,尤其在水相和无溶剂催化方面。
The main criteria for evaluating green catalytic synthesis methods include catalysts,reagents or solvents,reaction conditions,and post-treatment.With the continuous development of green chemistry,water-phase catalysis or solvent-free synthesis shows obvious advantages,and has attracted extensive attention in the synthesis of bis-indolyl methane derivatives.However,there is no review article report on the process of indolyl methane catalytic reaction and the related questions whether to use reagents or solvents.Therefore,this paper reviews the reactions for the synthesis of indolyl methane in the past decade.The purpose is to guide the development of greener and cleaner methods for the synthesis of indolymethane,especially under aqueous and solvent-free catalysis.
作者
吴之强
韩新宁
刘阳
王刚
詹海鹃
刘万毅
WU Zhi-Qiang;HAN Xin-Ning;LIU Yang;WANG Gang;ZHAN Hai-Juan;LIU Wan-Yi(School of Chemistry and Chemical Engineering,Ningxia Normal University,Guyuan,756000,China;State Key Laboratory of Highe-ficiency Utilization of Coal and Green Chemical Engineering,National Demonstration Center for Experimental Chemistry Education,College of Chemitry and Chemical Engineering,Ningxia University,Yinchuan 750021,China)
出处
《应用化学》
CAS
CSCD
北大核心
2021年第8期881-896,共16页
Chinese Journal of Applied Chemistry
基金
宁夏师范学院本科教学项目(No.NJYKCSZ2112)
宁夏师范学院校级科研项目(No.NXSFZDA2107)
西部地区一流大学建设重大创新项目(No.ZKZD2017003)
宁夏国家一流学科建设项目(No.NXYLXK2017A04)资助。
