摘要
The corrosion behavior of 2 A02 Al alloy under simulated marine atmospheric environment has been studied using mass-gain, scanning electron microscope/energy dispersive spectroscopy(SEM/EDS), laser scanning confocal microscopy, X-ray diffraction spectroscopy and localized electrochemical methods. The results demonstrate that the relationship between the corrosion induced mass-gain and the corrosion time is in accordance with the power rule. The mass-gain increases gradually during the corrosion time,while the corrosion rate decreases. With ongoing of the corrosion, corrosion products film changed from a porous to a compact structure. The various spectroscopic data show that the corrosion products films composed mainly of Al(OH)_3, Al_2O_3 and AlCl_3. The electrochemical corrosion behavior of the 2 A02 Al alloy was studied by electrochemical impedance spectroscopy(EIS).
The corrosion behavior of 2 A02 Al alloy under simulated marine atmospheric environment has been studied using mass-gain, scanning electron microscope/energy dispersive spectroscopy(SEM/EDS), laser scanning confocal microscopy, X-ray diffraction spectroscopy and localized electrochemical methods. The results demonstrate that the relationship between the corrosion induced mass-gain and the corrosion time is in accordance with the power rule. The mass-gain increases gradually during the corrosion time,while the corrosion rate decreases. With ongoing of the corrosion, corrosion products film changed from a porous to a compact structure. The various spectroscopic data show that the corrosion products films composed mainly of Al(OH)_3, Al_2O_3 and AlCl_3. The electrochemical corrosion behavior of the 2 A02 Al alloy was studied by electrochemical impedance spectroscopy(EIS).
基金
supported by the National Natural Science Fund of China (Nos.51622106 and 5167010950)
the National Key Basic Research and Development Plan of China (No.2014CB643303)
the International S&T Cooperation Program of China (ISTCP) (No.2014DFR50560)