摘要
大豆甙元磺酸钠与硫酸亚铁铵在一定条件下可以形成新的配合物,该配体与金属盐的摩尔比为1∶1时,可培养出大豆甙元磺酸铁(Ⅱ)配合物的单晶。通过X射线单晶衍射测定其结构,该配合物属于Triclinic晶系,P-1空间群,晶胞参数a=6.781 1(15),b=14.164(3),c=20.534(5),α=104.481(3)°,β=94.687(3)°,γ=94.458(2)°,V=1 893.2(8)3。
3'- dadzein sulfonic sodium and ammonium iron(Ⅱ) sulfate can form a new coordination complex under a certain condition. 3'- dadzein sulfonic iron( II) was obtained when the mole ratio of ligand and metallic salts mixed together was 1∶ 1. Single- crystal X- ray diffraction analysis revealed that the complex crystallizes in the Triclinic,P- 1 space group,with a = 6. 781 1( 15) A,b = 14. 164( 3) A,c = 20. 534( 5) A,α = 104. 481( 3) °,β = 94. 687( 3) °,γ = 94. 458( 2) °,V = 1 893. 2( 8) A^3.
出处
《河池学院学报》
2016年第2期29-33,共5页
Journal of Hechi University
基金
广西高校中青年教师基础能力提升项目(KY2016LX290)
河池学院科研基金重点资助项目(2013ZA-N004)
河池学院青年基金资助课题(2014QN-N011)