摘要
选取硼酸高温脱水后的混合物作为填料,与高岭土、滑石粉、铝粉等填料制备了以有机硅树脂为基料,可以耐受800℃的耐高温防护涂层并测试了涂层的各项性能。为研究硼酸混合物在涂层高温灼烧过程中的作用机理,对涂层在经200℃固化、500℃高温灼烧和700℃高温灼烧后的表层形貌、元素和涂层物质变化情况进行分析。阐明了涂层中有机硅树脂上的有机基团会在500℃时大量分解。硼酸混合物在高温下,会以熔融态填充有机硅树脂分解挥发产生的空隙,并粘接其他颜填料,但是涂层表面会有硼酸混合物脱水造成的少量凹陷存在。
Using silicone resin as base stock, using dehydrated boric acid mixture,kaolin,talcum powder and aluminum powder as fillers, a high temperature coating which can resist 800 ℃ was prepared. And every performance of the coating was tested. In order to research the action mechanism of boric acid mixture in high temperature calcination process of the coating, changes of the surface morphology and composing elements of the coating during solidifying under 200 ℃ and calcining under 500 ℃ and 700 ℃ were analyzed. The results show that, lots of organic groups on the organosilicon resin can be decomposed at 500 ℃;under high temperature, boric acid mixture in the molten state can fill the voids of the organosilicon resin produced by decomposition of organic groups, but a small amount of pits on surface of the coat will be formed by dehydration of boric acid mixture.
出处
《当代化工》
CAS
2015年第2期227-230,共4页
Contemporary Chemical Industry
基金
总后勤部基金资助项目
BX110C016
CSTC2012GG-SFGC00002
关键词
耐高温涂层
硼酸
有机硅树脂
反应机理
High temperature coatings
Boric acid
Silicone resin
Reaction mechanism
