摘要
NaHSO4和H2SO4能够作为酯化反应的催化剂,本文研究了以乙酸和正丁醇为原料,NaHSO4和浓H2SO4为复合催化剂合成乙酸正丁酯。最佳反应条件为:酸醇摩尔比n(乙酸):n(正丁醇)为1:1.65,催化剂用量为1.65g,复合催化剂中Na HSO4与浓H2SO4之比为1:0.17,反应时间125min,酯化率最高可达97.6%。
The sodium bisulfate and concentrated sulfuric acid can be used as a catalyst for esterification. Using acetic acid and n-butyl as raw material, sodium bisulfate and sulfuric acid catalyst for the synthesis of n-butyl acetate compound were studied. The optimum reaction conditions are as follows： acid molar ratio n（acetic acid）∶n（n-butyl）was 1：1.65, the amount of catalyst 1.65 g, Complex catalyst in concentrated sulfuric acid and sodium hydrogen sulfate ratio of 1：0.17, and the reaction time was one hundred and twenty minutes（125min）. Esterification rate can be up to 97.6%.
出处
《化学工程师》
CAS
2014年第11期79-81,共3页
Chemical Engineer
关键词
乙酸正丁酯
合成
复合催化剂
酯化率
n-butyl acetate
synthesis
complex catalyst
esterification rate
