摘要
本文报道了镧(Ⅲ)、铈(Ⅲ)与N,N’—亚乙基二(2—羟基—3—甲氧基苯甲亚胺)和N,N’,—邻亚苯基二(2—羟基—3—甲氧基苯甲亚胺)反应形成的固态配合物,通过元素分析、摩尔电导、红外光谱、电子光谱和热谱等研究了配合物的组成和性质。这些新配合物的组成可表示为:[LaL(H_2O)_2]NO_3和Ce_2L·nH_2O(L=MSEA或MSPA,n=0或4)。
The new complexes of Lanthanum (III) and Cerium(III) with N,N' -Ethylenebis(3 -Methoxysalicylidenemine) (H2MSEA)or N, N' - o - Phenylenebis(3 - Methoxysalicylideneimine) (H2MSPA) have been prepared. The complexes have been characterized by Elementary Analysis,Conductivity , Infrared Spectra, Electronic Spectra and Differential Thermal Analysis. The results indicate that their compositions are LaL(H2O)2NO3and Ce2L3 nH2O (L=MSEA or MSPA,n = 0,4) , respectively.
出处
《湖北大学学报（自然科学版）》
CAS
1991年第2期155-158,共4页
Journal of Hubei University：Natural Science
关键词
镧
铈
西佛碱配合物
合成
Lanthanum( III ), Cerium (III ), Diamine Schiff Bases,Synthesis.
