摘要
利用“原位生成”合成法，在Ｃｕ（ＣｌＯ４）２·６Ｈ２Ｏ的存在下，乙酰丙酮和对苯二胺反应，制得了一种新颖的西佛碱配合物〔Ｃｕ（Ｈ２Ｏ）２Ｌ〕（ＣｌＯ４）２（Ｌ＝ＯＨＮＮＮＯ），并通过元素分析数据及热重、摩尔电导、红外光谱、磁化率对其结构进行了表征，发现乙酰丙酮和对苯二胺生成了“１＋２”西佛碱，同时其中的未缩合氨基发生了氧化反应。
One novel Schiff base complex Cu(H 2O) 2L (ClO 4) 2(L=P-ON-C 6H 4-R,R=2-methyl-1-aza-3-penten-4-olate)formed by acetylacetone and p-phenylene diamine in the presence of copper perchlorate hexahydrate was synthesized.Based on the elemental analysis data obtained and the characterization of the thermogravimetric,molar conductivity,infrared spectral and magnetic susceptibility,it was concluded that while the '1+2'Schiff base was yielded from acetylacetone and p-phenylene diamine,the non-condensed amino group was oxidyzed into nitroso substituent.
出处
《山东师范大学学报（自然科学版）》
CAS
1996年第4期61-63,共3页
Journal of Shandong Normal University(Natural Science)
