摘要
通过溶液法制备了不同比例的聚己内酯/α-环糊精(PCL/α-CD)络合物,并通过热压法制备了PCL/α-CD络合物薄膜。分别使用傅里叶变换红外光谱仪(ATR-FTIR)、差示扫描量热分析仪(DSC)、透湿仪和透氧仪对不同比例的PCL/α-CD络合物薄膜的热性能、力学性能及阻隔性能进行研究。红外数据表明PCL和α-CD同时存在于络合物中。随着α-CD含量的增加,PCL/α-CD络合物的结晶度逐渐降低,薄膜的氧气阻隔性和水蒸气阻隔性逐渐增加,并且薄膜的氧气阻隔性增加的效果大于水蒸气阻隔性增加的效果。
PCL with α-CD inclusion complex （PCLIC） film was prepared by solution method with different ratios, and PCLIC film was prepared through hot-pressing method. The thermal, mechanical and barrier properties of PCLIC films were characterized by attenuated total reflectance fourier transformed infrared （ATR-FTIR）, differential scanning calorimetry（DSC）, oxygen and moisture permeation analyzer. The ATR-FTIR reveals that PCL and α-CD coexist in complexes. With increasing the content of α-CD, the crystallinity of PCL decreases. The oxygen and water vapor barrier properties of PCLIC film gradually increase with the increasing of α-CD content, and then the effect of oxygen barrier increases larger than that of water vapor barrier.
出处
《塑料科技》
CAS
北大核心
2014年第6期76-79,共4页
Plastics Science and Technology
基金
内蒙古自治区高等学校科学研究项目(NJZY11058)
国家自然科学基金(No.51163010)
内蒙古草原英才科研基金(2011)
关键词
聚己内酯
Α-环糊精
热性能
力学性能
阻隔性能
Polycaprolactone
α-Cyclodextrin
Thermal property
Mechanical property
Barrier property
