期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

2,6-吡啶二羧酸铜配合物的合成与晶体结构分析 被引量：3

Synthesis and Crystal Structure of Polymer Copper 2,6-pyridinediylbis
下载PDF
导出
摘要 利用水热法合成了一个结构新颖的2,6-吡啶二羧酸铜配合物,通过元素分析和TG分析确定其化学式为[Cu4(pdc)4(H2O)7].3H2O,利用FTIR光谱和X射线单晶衍射对其结构进行了表征.分析结果表明,该化合物呈现出二维层状结构,金属铜离子以五或六配位方式存在,2,6-二羧酸以三齿配体和铜离子相连. A novel Copper 2,6 -pyridinediylbis coordination polymers [ Cu5 （pdc）4 （H2O）7 ] · 3H2O were synthesized by hydrothermal method and characterized by elementary analysis, and TGA. FFIR and X -ray crystallography reveals that complex is a 2D layered network. Cu is six - coordinate or five - coordinate. 2, 6 -pyridinediylbis act as a tridendate ligand bond with Cu ion.
作者 苏占华 王春梅 赵志凤 顾佳 周百斌
机构地区 哈尔滨师范大学
出处 《哈尔滨师范大学自然科学学报》 CAS 2011年第1期69-72,共4页 Natural Science Journal of Harbin Normal University
基金 黑龙江省教育厅项目(11531249)
关键词 水热合成 2 6-二羧酸 晶体结构 Hydrothermal method 2,6 - pyridinediylbis Crystal structure
分类号 O484.1 [理学—固体物理]
  • 相关文献

参考文献8

  • 1ZengM H ,ZhangW X,Sun X Z,et al. Spin Canting and Metamagnetism in a 3D Homometallic Molecular Material Constructed by Interpenetration of Two Kinds of Cobalt( II ) - Coordination -Polymer Sheets[J] .Angew Cbem Int Ed ,2005, 44 : 3079 -3082. 被引量：1
  • 2Xu H B ,Wang B W,Pan F ,et al . Stringing Oxo -Centered Trinuclear [ MnIII30] Units into Single- Chain Magnets with Formate or Azide Linkerset al[ J ] . Angew Chem Int Ed , 2007,46:7388-7392. 被引量：1
  • 3ZhaoB ,Cheng P ,Dai Y,et al. Poly [(5-2,6-dimethylpyridine - 3,5 - Dicarboxy lato) zinc ] [ J ] . Angew Chem Int Ed ,2003 ,42:934-936. 被引量：1
  • 4Zhao B ,Cheng P ,Chen X,et al. Design and Synthesis of 3d -4f Metal - Based Zeolite - type Materials with a 3D Nanotubular Structure Encapsulated "Water" Pipe[ J] . J Am Chem Soc ,2004 ,126:3012-3013. 被引量：1
  • 5Cui S X, Zhao Y L , Li B , et al . Structural and magnetic properties of one - dimensional polymeric Co^II complexes[ J]. Polyhedron ,2008 ,27 : 671 -678. 被引量：1
  • 6Cui S X,Zhao Y L ,Zhang J P ,et al. Bipyridyl Second Lig- and Dependent Structural and Magnetic Properties of Cu( II) Complexes with Pyridine - 2,6 - dicarboxylate and Water Molecule as First Ligand[J] . Cryst Growth Des ,2008 ,8 : 3803 - 3809. 被引量：1
  • 7Cui S X,Zhao Y L ,Zhang J P ,et al. Surface curvatures and diffiaction profiles of sagittally bent Laue crystals [ J ] . Acta Cryst ,2007 ,E63 :m3102. 被引量：1
  • 8Zhao Y L ,Cui S X,Zhang J P ,et al. Structural and magnetic property of one - dimensional polymeric Ni ( II ) complex[ J ]. J Mol Struct ,2008 ,873:191-194. 被引量：1

同被引文献21

  • 1Y.H.Zhou 1) ,Y.Y.Feng 2) and H.Y.Lu 2) 1)Department of Physics Nanjing Normal University, Nanjing 210097,China 2)Physics and Ch寁O P T I C A L P R O P E R T I E S O F Ge O2 A N D Ge N A N O C R Y S T A L S Y. H. Zhou1) , Y. Y. Feng2).OPTICAL PROPERTIES OF GeO_2 AND Ge NANOCRYSTALS[J].Acta Metallurgica Sinica(English Letters),1999,12(5):1164-1165. 被引量：23
  • 2林曦.新型取代缺位钨杂多酸盐的合成与结构[J].福建师范大学学报（自然科学版）,2005,21(1):70-74. 被引量：2
  • 3宋会花,杨芳,王继业,石士考.均苯三甲酸铽掺杂(钇、钆)配合物的合成及荧光性质[J].光谱学与光谱分析,2007,27(10):2093-2097. 被引量：7
  • 4KUSRINI E, SALEH M I, ADNAN R, et al. Ternary complexes of neodymium( 11I ) and samarium( III ) picrate triethylene glycol: Structural, spectroscopic, and photoluminescent properties [J ] . Journal of Inclusion Phenomena and Maerocyclie Chemistry, 2012, 74(1-4) : 425-436. 被引量：1
  • 5KUSRINI E, SALEH M I, ADINATA D, et ah CrystaI structure and photoluminecencc propertie of gadolinium picrate triethyl- ene glycol complex [J]. Journal of Chemical Crystallography, 2012,42(8) ..859-865. 被引量：1
  • 6SOUZA A P,RODRIGUES L,BRITO H F,et al. Novel europium and gadolinium complexes with methaneseleninate as ligand: Syn thesis, characterization and spectroscopic study [J]. Inorganic Chemistry Communications, 2012,15(2012) : 97-101. 被引量：1
  • 7ALIZADEH M H,MIRZAEI M,RAZAVI H. 2[YNetwork of in organic-organic hybrid material built on Keggin type polyoxomet- atlate and amino acid: [ L-C2 H6 N()2 ]a [ (PO4) Mo12 O:6 ] " 5 H2 O [J]. Materials Research Bulletin, 2008,43 (3) : 546-555. 被引量：1
  • 8POPE M T. Heteropoly and lsopoly Oxometalates[M]. Springer, Berlin, 1983. 被引量：1
  • 9HILL C L, PROSSER- MCCARTH A C M. Homogeneous catalysis by transition metal oxygen anion clusters[J]. Coordination Chem istry Reviews, 1995,143 : 407-455. 被引量：1
  • 10AL1ZADEH M H,RAZAVI H,BAMOHARRAM F F,et al. No- vel catalytic acetylation of alcohols with preyssler's anion[J]. Ki netics and Catalysis,2003,44(4) :524-528. 被引量：1

引证文献3

二级引证文献3

哈尔滨师范大学自然科学学报
2011年 第1期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部