摘要
以乙二胺为模板,利用水热技术合成了具有链状结构的新型配合物(C2H10N2)[Mo3O10].晶体的X射线衍射分析结果表明,配合物(C2H10N2)[Mo3O10]为单斜晶系,其晶胞参数为:a=8.0865(2),b=14.4902(2),c=8.9306(2),β=98.170(1)°,Z=4.(C2H10N2)[Mo3O10]由扭曲的MoO6八面体通过共顶点、共边、共面形成平行于a轴的平行长链而形成,乙二胺游离在该链之外,同时并对配合物的热稳定性和电化学性质进行了研究.
A novel coordination compound of （C2H10N2）[Mo3O10] was synthesized With ethylenediamine trimolybdate by hydrothermal methad.It crystallizes in the monoclinic system with a = 8.0865（2）,b = 14.4902（2） ,c=8.9306（2）,β = 98.170（1） °,and Z = 4.Its structure consists of hitherto un-known infnite chains running parallel to the a axis made up of distorted MoO6 octahedra connected by corners,edges,and faces.
出处
《哈尔滨师范大学自然科学学报》
CAS
2010年第5期60-62,共3页
Natural Science Journal of Harbin Normal University
关键词
配合物
水热合成
晶体结构
Coordination compounds
Hydrothermal Synthesis
Crystalline structure
