摘要
近年来,大量的碳硼烷和金属碳硼烷的成功合成,促进了多面体团簇的发展.IA族和Ⅷ族金属化合物与碳硼烷配体合成的14顶点金属碳硼烷拥有丰富多样的结构,对碳硼烷和金属碳硼烷的研究有重要作用.本文综述了14顶点IA族和Ⅷ族金属碳硼烷的合成和研究进展以及未来发展趋势.
Recently, significant progresses in the syntheses of carboranes and metallacarboranes open up new possibilities for the development of polyhedral clusters. Different types of 14-vertex metallacarboranes synthesized by IA and Ⅷ metals and ligands, play an important role in the carboranes and metallacarboranes' development. This review summarizes the advances in this growing research of the 14-vertex metallacarborane's achievements and perspectives.
出处
《曲阜师范大学学报(自然科学版)》
CAS
2010年第2期101-104,共4页
Journal of Qufu Normal University(Natural Science)