摘要
研究了CO偶联反应制草酸二甲酯(DMO)的本征反应动力学。根据最新的机理研究的结果,提出了新的本征动力学模型。根据动力学实验数据发现催化剂表面反应是CO偶联反应的控制步骤。此外,通过动力学研究获得了CO偶联反应制DMO的本征反应动力学方程。
Intrinsic kinetics of coupling reaction of carbon monoxide to dimethyl oxalate（DMO） was studied experimentally.Based on the latest works on reaction mechanism,a new intrinsic kinetic model was proposed.The experimental results showed that surface reaction on the catalyst was the rate-determining step.And,an intrinsic kinetic equation for the coupling reaction of carbon monoxide to DMO has been obtained.
出处
《天然气化工—C1化学与化工》
CAS
CSCD
北大核心
2010年第5期20-24,共5页
Natural Gas Chemical Industry
