摘要
不饱和醇是非常重要的有机合成中间体,可通过相应不饱和醛/酮催化加氢还原,其中氢转移还原反应最为简单高效。因此,制备高效醛/酮氢转移反应催化剂成为国内外研究的热点。氧化物催化剂在氢转移反应中具有良好的催化剂活性及选择性,文章综述了氧化物催化剂的制备方法及其应用情况,并对其发展趋势和应用前景作了展望。
The hydrogen transfer reduction of unsaturated aldehydes/ketones to the corresponding alcohols is distinguished by its exceptional chemoselectivity.So the sythesis of catalysts for the hydrogen transfer reduction has got considerable attention in recent years.Metal oxides has been found to be a highly activtive and stereoselective catalyst in the hydrogen transfer reduction.The synthetic methods and the applications of metal oxides are reviewed, and the developing prospects of metal oxides have also been discussed.
出处
《浙江化工》
CAS
2010年第6期10-14,共5页
Zhejiang Chemical Industry
关键词
不饱和醇
不饱和醛/酮
氧化物
氢转移
unsaturated alcohols
unsaturated aldehydes/ketones
oxides
hydrogen transfer
