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水中微量氰化物的测定方法——异烟酸-巴比妥酸主次波长光度法 被引量:2

Determination of Trace Cyanide in Water by Primary-secondary Wavelengthes Spectrophotometry with System of Isonicotinic Acid-Barbituric Acid
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摘要 根据异烟酸-吡唑啉酮和吡啶-巴比妥酸光度法测定水中氰化物的基本原理,将二者重新组合成异烟酸-巴比妥酸体系,采用主次波长光度法测定。该法具有室温显色,显色所需时间较短,有色溶液稳定,对环境污染小,灵敏度高等优点,其最低检测限为0001mg/L。特别适合于饮用水、生活污水、工业废水中微量氰化物的测定。通过对实际样品分析,与原方法进行比较,结果令人满意。 According to the principle of determination of cyanide in water by isonicotinic acid-pyrazolone and pyridine-barbituric acid,a new isonicotinic acid-barbituric acid system has been found and was applied to the determination by primary-secondary wavelengthes spectrophotometry.The proposed method has advantages of colour developing at room temperature and in a short time,stable colour of solution,smaller pollution,high sensitivity,etc.The detection limit of the method is 0 001 mg/L.It is suitable for analysis of drinking water,domestic sewage and industrial waste water.The method has been applied to the determination of practical samples with satisfactory results.
作者 程永华 胡娟
出处 《分析测试学报》 CAS CSCD 1998年第6期69-71,共3页 Journal of Instrumental Analysis
关键词 异烟酸 巴比妥酸 水样 氰化物 光度法 水质监测 Primary-secondary wavelength,Isonicotinic acid,Barbituric acid,Water,Cyanide,Spectrophotometry
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