期刊文献+

二氧化钒薄膜制备及其热致变发射率特性研究 被引量:7

Preparation and Properties of Variable Emissivity Thermochromic VO_2 Thin Films
下载PDF
导出
摘要 通过溶胶-凝胶和真空热处理工艺在石英基底上制备了二氧化钒薄膜,对制备出的薄膜进行了X射线衍射及X射线光电子能谱分析,结果表明所制备出的薄膜价态单一,纯度较高,薄膜为多晶态,晶粒尺寸约为27 nm。利用红外热像仪拍摄了薄膜在不同温度下的红外热图并计算了发射率,结果表明二氧化钒薄膜7.5~14μm波段发射率在相变时发生突变,突变量可达0.6,具有优异的热致变发射率性能,在红外自适应伪装等领域应用前景广阔。 The VO2 thin film was prepared by inorganic sol-gel process and vacuum post-annealing treatment. The film was characterized by X-ray diffraction and X-ray photoelectron spectroscopy, and results show that the pure VO2 thin film without other valences has been prepared. The film is polycrystalline with grain size about 30 nm. The thermal images of the VO2 thin film at different temperatures were derived using thermal imager and the emissivity was calculated. It was found that 7.5- 14 um emissivity of the VO2 thin film could change abruptly by about 0.6 during the phase transition, which shows that the VO2 thin film exhibits excellent thermochromic properties and is meaningful in the adaptive infrared camouflage.
出处 《红外技术》 CSCD 北大核心 2010年第3期181-184,共4页 Infrared Technology
基金 武器装备预研基金资助项目
关键词 二氧化钒 发射率 热致变色 薄膜 红外伪装 vanadium dioxide, emissivity, thermochromic, thin film, infrared camouflage
  • 相关文献

参考文献10

  • 1F. J. Morin. Oxides which show a metal-to-insulator transition at the neel temperature[J]. Phys. Rev. Lett., 1959(3): 34. 被引量:1
  • 2W. Burkhardt, T. Christmann, B. K. Meyer, et al. W-and F-doped VO2 films studied by photoelectron spectrometry[J]. Thin Solid Films, 1999, 345: 229. 被引量:1
  • 3S. W. Lu, Hou L S, Gan F X. Surface analysis and phase transition of gel-derived VO2 thin films[J]. Thin Solid Films, 1999, 353: 40-44. 被引量:1
  • 4刘东青,郑文伟,程海峰,刘海韬.热致变色二氧化钒薄膜的研究进展[J].材料导报,2009,23(21):105-109. 被引量:11
  • 5D. C. Yin, N. K. Xu, J. Y. Zhan, et al. High quality vanadium dioxide films prepared by an inorganic sol-gel method[J]. Mater Res Bull, 1996, 31:335. 被引量:1
  • 6曹义,程海峰,郑文伟,才鸿年,成绍军.基于红外热像仪的涂层波段发射率测量[J].红外技术,2007,29(6):316-319. 被引量:19
  • 7D. Q. Liu, W. W. Zheng, H. F. Cheng, et al. Thermoehromic VO2 thin film prepared by post annealing treatment of V2O5 thin film[J]. Adv. Mater. Res, 2009, 79-82: 747-750. 被引量:1
  • 8J. Z: Yan, Y. Zhang, W. X. Huang, et al. Effect of Mo-W co-doping on semiconductor-metal phase transition temperature of vanadium dioxide film[J]. Thin Solid Films, 2008, 516: 8554-8558. 被引量:1
  • 9刘东青,郑文伟,程海峰,刘海韬,杜盼盼.热致变发射率VO_2涂层研究及应用[J].新技术新工艺,2008(11):117-119. 被引量:3
  • 10L. J. Jiang. A mieromachined thermo-optical light modulator based on semiconductor-to-metal phase transition[D]. United States: New Jersey Institute of Tectmology, 2004. 被引量:1

二级参考文献58

  • 1王栋,林耀,顾利霞.纳米锑掺杂二氧化锡水悬浮液性质的研究[J].中国粉体技术,2004,10(1):10-14. 被引量:25
  • 2王自荣,孙晓泉.红外隐身涂层的热图研究[J].表面技术,2004,33(6):65-66. 被引量:15
  • 3Guinneton F,Sauques L,Valmalette J C,et al. Comparative study between nanocrystalline powder and thin film of vanadium dioxide VO2: electrical and infrared properties [J]. Phys Chem Solids, 2001,62 : 1229. 被引量:1
  • 4Tsang C, Manthiram A. Synthesis of Nanocrystalline VO2 and Its Electrochemical Behavior in Lithium Batteries [J]. ElectrochemSoc,1997,144(2):520. 被引量:1
  • 5刘永峙 于名讯 孙芳兵 等.红外隐身材料的研究进展.功能材料,2006,37:1138-1138. 被引量:1
  • 6Morin F J. Oxides which show a metal-to-insulator transition at the neel temperature[J]. Phys Rev Lett, 1959, (3) : 34. 被引量:1
  • 7Fillingham P J. Domain structure and twinning in crystals of vanadium dioxide[J]. J Appl Phys, 1967,38 (12) : 4823. 被引量:1
  • 8Becker M F, Buckman A B, Walser R M. Femtosecond laser excitation of the semiconductor-metal phase transition in VO2[J]. Appl Phys Lett,1994,65(12):1507. 被引量:1
  • 9Guinneton F, Sauques L, Valmalette J C, et al. Role of surface defects and mierostructure in infrared optical properties of thermoehromic VO2 materials[J]. J Phys Chem Solids, 2005,66:63. 被引量:1
  • 10Jin P, Nakao S, Tanemur A S. Tungsten doping into vanadium dioxide thermochromic films by high-energy ion implantation and thermal annealing [J]. Thin Solid Films, 1998,3241151. 被引量:1

共引文献30

同被引文献101

引证文献7

二级引证文献34

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部