摘要
用氧化物对NaZSM-5分子筛进行改性来调节其表面酸碱性,已越来越受到人们重视,本文报道用Li2O、La2O3双组份对NaZSM-5进行改性,并将改性分子筛用作甲醇和碳酸乙烯酯(简称BC)反应制碳酸二甲酯(简称DMC)体系的催化剂。文献报道用作此反应...
Modification of NaZSM 5 by Li 2O and La 2O 3 was made.Characterication of modified NaZSM 5 by XRD and IR showed that addition of Li 2O cause the change of structure of ZSM 5 zeolite.The activity experiments results indicated that Li La/NaZSM 5 catalyst showed much better transeterification activities than NaZSM 5.
出处
《化学研究与应用》
CAS
CSCD
1998年第5期515-517,共3页
Chemical Research and Application
关键词
碳酸乙烯酯
碳酸二甲酯
酯交换
催化剂
锂
镧
Dimethyl carbonate,Ethylene carbonate,Transesterification,Catalyst