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β-环糊精-环氧氯丙烷高聚物的交联度和亲水性分析 被引量:2

ANALYSIS OF THE CROSSLINKINGDEGREE AND HYDROPHILOCITY FOR β-CYCLODEXTRIN-EPICHLOROHYDRIN POLYMER
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摘要 通过改变合成条件,制备一系列具有不同交联度的β-环糊精-环氧氯丙烷高聚物(β-CDEP),以元素分析法确定聚合物中β-环糊精单体含量,以标准方法测定聚合物的吸水率用以表征亲水性和交联度,该聚合物的吸水率(X)和摩尔交联度(m)两个参数之间的数学关系可近似地用线性方程表示. β-Cyclodextrins (β-CDs) were immobilized by crosslinking with epichlorohydrins to produce a series of β-CDEP with various crosslinkingdegrees through the change of synthetical conditions. The molar ratio of the epichlorohydrin to β-cydodextrin (m,molar crosslinkingdegree) for each polymeric product was standardized by corresponding elemental analysis, The waterabsorption of the polymer was determined by standard method and was utilized to characterize the crosslinkingdegree. The correspondent correlation to two types of property parameter can be got
出处 《郑州大学学报(自然科学版)》 CAS 1997年第4期73-76,共4页 Journal of Zhengzhou University (Natural Science)
关键词 环糊精 高聚物 交联度 β-CDEP 环氧氯丙烷 cyclodextrin polymer waterabsorption analysis of crosslinkingdegree
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