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电子封装材料表面化学制备高导电率聚吡咯薄膜的研究 被引量:1

Chemical synthesis of high electrical conductivity polypyrrole film on the surface of electronic packaging materials
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摘要 研究了在环氧树脂塑料封装材料表面制备导电聚吡咯(PPy)薄膜的化学聚合方法,分析了影响聚吡咯薄膜微观形貌、附着力及电导率的因素。用四探针法测聚吡咯薄膜的电导率,并用扫描电子显微镜(SEM)、红外光谱(IR)、X射线光电子能谱(XPS)进行了表征。通过对电子封装材料的表面预处理与改性,制得了附着性好、均匀连续的聚吡咯薄膜,经掺杂电导率达到了45.10S/cm。 Polypyrrole film was prepared on the surface of epoxy resin plastic electronic packaging materials by chemical polymerization method. Effect factors of micro-morphology, adhesion and conductivity of polypyrrole film were analyzed. The conductivity of PPy film was measured by the four-point probe method and the samples were characterized by scanning electron microscopy (SEM), infrared spectrum (IR) and X-ray photoelectron spectroscopy (XPS). A homogeneous and compact polypyrrole film was obtained through pretreatment and mod- ification by surfactant to the surface of electronic packaging,and the conductivity got to 45.10S/cm by doping.
出处 《功能材料》 EI CAS CSCD 北大核心 2006年第7期1051-1053,共3页 Journal of Functional Materials
基金 国家自然科学基金资助项目(60071027) 天津市自然科学基金资助项目(023603811)
关键词 聚吡咯薄膜 电子封装材料 化学聚合 polypyrrole film electronic packaging materials chemical polymerization
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