摘要
以ω─甲酰基莰烯经两步氢化合成的内型异莰烷基甲醇为原料，先制得了内型异莰烷基－溴甲烷，再使后者和醇钠反应合成了７个标题化合物，均属新化合物。并且用相转移催化的方法进行了该类化合物的合成，结果良好。各产品纯化后进行了ＩＲ、￣１ＨＮＭＲ与ＭＳ分析。
Seven new endo-8-alkoxylmethylisocamphane were synthesized by Williamson reaction between endo-isocamphanylbromomethane (2) and sodium alcoholate. (2) was prepared through bromination of endo-isocamphanylmethanol. which could be derived from ω-formylcamphene. Using phase transfer catalyst,the above Williamson reaction was improved. All products have been purified and identified with IR as well as ￣1H NMR and MS.
出处
《林产化学与工业》
EI
CAS
CSCD
北大核心
1996年第1期7-10,共4页
Chemistry and Industry of Forest Products
基金
江西省自然科学基金
关键词
合成法
相转移催化
香料
烷氧基
甲基
异莰烷
Williamson reaction
Phase transfer catalysis
Synthetic perfume
