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双酚F环硫-环氧树脂固化物的性能研究 被引量:5

Study on properties of cured compound for bisphenyl F epoxy-episulfide resin system
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摘要 以甲基六氢邻苯二甲酸酐(MeHHPA)为固化剂,N,N二甲基苄胺为固化促进剂,在一定的固化条件下,对双酚F环硫环氧树脂进行固化实验,探讨了固化机理。并对双酚F环硫环氧树脂固化物的吸水性、拉伸强度、剥离强度和玻璃化温度进行分析测试,结果表明,与双酚F环氧树脂相比,相应的双酚F环硫环氧树脂具有更高的拉伸强度、剥离强度和玻璃化温度以及较低的吸水性。 Using MeHHPA as the hardener and N,N-dimethyl benzylamine as the catalyst,the curing behavior and reaction mechanism of bisphenyl F epoxy-episulfide resin system were studied under a cured condition. Glass transition temperature of cured compounds were investigated using DSC.The effect of episulfide value of bisphenyl F epoxy-episulfide resins on the properties,such as water absorption,glass transition temperature,tensile strengh and peel strengh was investigated,and the results showed that bisphenyl F epoxy-episulfide resin system has some significant advantages over common epoxy resins:lower water absorption,higher glass transition temperature,higher tensile strengh and more rapid low temperature curing.
机构地区 武汉工程大学
出处 《粘接》 CAS 2005年第3期7-9,共3页 Adhesion
基金 浙江省瑞安市科技局重大科技项目(2004-4009)
关键词 双酚F环硫-环氧树脂 固化 性能 bisphenyl F epoxy-episulfide resin curing property study
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参考文献8

  • 1Fujishiro Koichi, Ogata Hiroshi. Kaji Masashi. Episulfide compounds and fast-curable thermosetting resin compositions having excellent resistance to heat and moisture and high refractive index[P]. JP 2002 338564 A2. 2003-12-27. 被引量:1
  • 2Yoshimura Yuichi, Takeuchi Motoharu. Horikoshi Hiroshi. Novel episulfides, their compositions, optical materials therefrom, and method for manufacture of heat-and impact-resistant polymers with high refractive index and Abbe number[P]. JP 2003026674 A2. 2003-07-29. 被引量:1
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