摘要
本文着重阐述了醛、酮与格氏试剂的一些重要的非常规反应,以及反应中的立体化学问题。并运用前线轨道理论及单电子转移理论,对目前争论较多的该反应的机理作了分析。
In this paper, some uncoventional reaction of aldehyde and ketone with Grignard reagent and the question of stereochemistry in the reaction was stueied chiefly. The mechamism of the reaction was shown and analysed by the theories of front orbit and single-electron transfer.
关键词
醛
酮
格氏试剂
格氏反应
Aldehyde, ketone,grignard reagent, grignard reaction.