X-ray photoelectron spectroscopy(XPS)is an important characterization tool in the pursuit of controllable fluorination of two-dimensional hexagonal boron nitride(h-BN).However,there is a lack of clear spectral interpr...X-ray photoelectron spectroscopy(XPS)is an important characterization tool in the pursuit of controllable fluorination of two-dimensional hexagonal boron nitride(h-BN).However,there is a lack of clear spectral interpretation,and seemingly conflicting measurements exist.To discern the structure−spectroscopy relation,we performed a comprehensive first-principles study on the boron 1s edge XPS of fluorinated h-BN(F-BN)nanosheets.By gradually introducing 1−6 fluorine atoms into different boron or nitrogen sites,we created various F-BN structures with doping ratios ranging from 1 to 6%.Our calculations reveal that fluorines landed at boron or nitrogen sites exert competitive effects on the B 1s binding energies(BEs),leading to red or blue shifts in different measurements.Our calculations affirmed the hypothesis that fluorination affects 1s BEs of all borons in theπ-conjugated system,opposing the transferability from h-BN to F-BN.Additionally,we observe that BE generally increases with higher fluorine concentration when both borons and nitrogens are nonexclusively fluorinated.These findings provide critical insights into how fluorination affects boron’s 1s BEs,contributing to a better understanding of fluorination functionalization processes in h-BN and its potential applications in materials science.展开更多
The impact of vibrations due to underground trains on Beijing metro line 15 on sensitive equipment in the Institute of Microelectronics of Tsinghua University was discussed to propose a viable solution to mitigate the...The impact of vibrations due to underground trains on Beijing metro line 15 on sensitive equipment in the Institute of Microelectronics of Tsinghua University was discussed to propose a viable solution to mitigate the vibrations.Using the state-of-the-art three-dimensional coupled periodic finite element-boundary element(FE-BE) method,the dynamic track-tunnel-soil interaction model for metro line 15 was used to predict vibrations in the free field at a train speed of 80 km/h.Three types of tracks(direct fixation fasteners,floating slab track and floating ladder track) on the Beijing metro network were considered in the model. For each track,the acceleration response in the free field was obtained.The numerical results show that the influence of vibrations from underground trains on sensitive equipment depends on the track types.At frequencies above 10 Hz,the floating slab track with a natural frequency of 7 Hz can be effective to attenuate the vibrations.展开更多
An algebraic method with symbolic computation is devised to uniformly construct a series of exact solutions of the （2＋1）-dimensional Caudrey-Dodd-Gibbon-Kotera-Sawda equation. The solutions obtained in this paper i...An algebraic method with symbolic computation is devised to uniformly construct a series of exact solutions of the （2＋1）-dimensional Caudrey-Dodd-Gibbon-Kotera-Sawda equation. The solutions obtained in this paper include solitary wave solutions, rational solutions, triangular periodic solutions, Jacobi and Weierstrass doubly periodic solutions. Among them, the Jacobi periodic solutions exactly degenerate to the solutions at a certain limit condition. Compared with most existing tanh method, the method used here can give new and more general solutions. More importantly, this method provides a guldeline to classifj, the various types of the solution according to some parameters.展开更多
2N line-soliton solutions of the (3+1)-dimensional Jimbo-Miwa equation can be presented by resorting tothe Hirota bilinear method.In this paper,N periodic-soliton solutions of the (3+1)-dimensional Jimbo-Miwa equation...2N line-soliton solutions of the (3+1)-dimensional Jimbo-Miwa equation can be presented by resorting tothe Hirota bilinear method.In this paper,N periodic-soliton solutions of the (3+1)-dimensional Jimbo-Miwa equationare obtained from the 2N line-soliton solutions by selecting the parameters into conjugated complex parameters in pairs.展开更多
基金support from the National Natural Science Foundation of China(Grant No.12274229)is greatly acknowledged.
文摘X-ray photoelectron spectroscopy(XPS)is an important characterization tool in the pursuit of controllable fluorination of two-dimensional hexagonal boron nitride(h-BN).However,there is a lack of clear spectral interpretation,and seemingly conflicting measurements exist.To discern the structure−spectroscopy relation,we performed a comprehensive first-principles study on the boron 1s edge XPS of fluorinated h-BN(F-BN)nanosheets.By gradually introducing 1−6 fluorine atoms into different boron or nitrogen sites,we created various F-BN structures with doping ratios ranging from 1 to 6%.Our calculations reveal that fluorines landed at boron or nitrogen sites exert competitive effects on the B 1s binding energies(BEs),leading to red or blue shifts in different measurements.Our calculations affirmed the hypothesis that fluorination affects 1s BEs of all borons in theπ-conjugated system,opposing the transferability from h-BN to F-BN.Additionally,we observe that BE generally increases with higher fluorine concentration when both borons and nitrogens are nonexclusively fluorinated.These findings provide critical insights into how fluorination affects boron’s 1s BEs,contributing to a better understanding of fluorination functionalization processes in h-BN and its potential applications in materials science.
基金Projects(50538010,50848046) supported by the National Natural Science Foundation of ChinaProject(BIL07/07) supported by the Research Council of K.U.Leuven and the National Natural Science Foundation of China
文摘The impact of vibrations due to underground trains on Beijing metro line 15 on sensitive equipment in the Institute of Microelectronics of Tsinghua University was discussed to propose a viable solution to mitigate the vibrations.Using the state-of-the-art three-dimensional coupled periodic finite element-boundary element(FE-BE) method,the dynamic track-tunnel-soil interaction model for metro line 15 was used to predict vibrations in the free field at a train speed of 80 km/h.Three types of tracks(direct fixation fasteners,floating slab track and floating ladder track) on the Beijing metro network were considered in the model. For each track,the acceleration response in the free field was obtained.The numerical results show that the influence of vibrations from underground trains on sensitive equipment depends on the track types.At frequencies above 10 Hz,the floating slab track with a natural frequency of 7 Hz can be effective to attenuate the vibrations.
基金The project supported by the City University of Hong Kong Strategic Research under Grant No. 7001791
文摘An algebraic method with symbolic computation is devised to uniformly construct a series of exact solutions of the （2＋1）-dimensional Caudrey-Dodd-Gibbon-Kotera-Sawda equation. The solutions obtained in this paper include solitary wave solutions, rational solutions, triangular periodic solutions, Jacobi and Weierstrass doubly periodic solutions. Among them, the Jacobi periodic solutions exactly degenerate to the solutions at a certain limit condition. Compared with most existing tanh method, the method used here can give new and more general solutions. More importantly, this method provides a guldeline to classifj, the various types of the solution according to some parameters.
基金supported by the State Key Basic Research Program of China under Grant No.2004CB318000National Natural Science Foundation of China under Grant No.10771072
文摘2N line-soliton solutions of the (3+1)-dimensional Jimbo-Miwa equation can be presented by resorting tothe Hirota bilinear method.In this paper,N periodic-soliton solutions of the (3+1)-dimensional Jimbo-Miwa equationare obtained from the 2N line-soliton solutions by selecting the parameters into conjugated complex parameters in pairs.
