In this study, we developed a novel angularbased spatially resolved laser-induced breakdown spectroscopy(ABSR-LIBS) technique. This new method allows the spatially resolved spectroscopic properties of laserinduced pla...In this study, we developed a novel angularbased spatially resolved laser-induced breakdown spectroscopy(ABSR-LIBS) technique. This new method allows the spatially resolved spectroscopic properties of laserinduced plasma to be investigated using different angles and polar distances with a spatially adjustable fiber optics probe. The experimental evaluations suggested that the intensity of the Al signal distributions in the ‘‘side-view''depended greatly on the angle of the collection probe. The location of a collection probe at 50° would facilitate efficient spectral collection and minimize the disturbance of the plasma plume. The spectral signals in the plasma emissions had different distribution at various polar distances using the same collection angle, and the highest signal intensity was observed between 15 and 35 mm polar distances. This ABSR-LIBS technique improved both the LIBS signal and the maximum emission intensity of Al atoms by several times at the best spatial position in our experimental conditions. Furthermore, we successfully obtained well-resolved line emission spectroscopy signals without any external time delay using a nongated spectrometer based on the ABSR-LIBS system. We consider that the ABSR-LIBS technique has great potential for obtaining new insights with laser-induced plasma instruments and it could facilitate the development of a low-cost instrument.展开更多
An arc model considering deviations from thermodynamic and chemical equilibrium has been developed in order to achieve a better understanding of the arc plasma close to material surfaces.The model is based on unified ...An arc model considering deviations from thermodynamic and chemical equilibrium has been developed in order to achieve a better understanding of the arc plasma close to material surfaces.The model is based on unified consideration of the thermionic tungsten cathode,the arc region and the flat anode made of copper.The heat transfer within the electrodes is coupled with the plasma through the energy fluxes onto the electrode boundaries.Electrical characteristics of an 8 mm long free-burning arc are presented along with findings from spectroscopic measurements of the plasma emission in atmospheric pressure argon.The arc current varied from 60 A up to 200 A,and the gas flow rate was set at 12 L/min(at atmospheric pressure,room temperature).展开更多
基金supported by National Major Scientific Instruments and Equipment Development Special Funds (2011YQ030113)National Recruitment Program of Global Experts (NRPGE)+1 种基金the Hundred Talents Program of Sichuan Province (HTPSP)the Startup Funding of Sichuan University for setting up the Research Center of Analytical Instrumentation
文摘In this study, we developed a novel angularbased spatially resolved laser-induced breakdown spectroscopy(ABSR-LIBS) technique. This new method allows the spatially resolved spectroscopic properties of laserinduced plasma to be investigated using different angles and polar distances with a spatially adjustable fiber optics probe. The experimental evaluations suggested that the intensity of the Al signal distributions in the ‘‘side-view''depended greatly on the angle of the collection probe. The location of a collection probe at 50° would facilitate efficient spectral collection and minimize the disturbance of the plasma plume. The spectral signals in the plasma emissions had different distribution at various polar distances using the same collection angle, and the highest signal intensity was observed between 15 and 35 mm polar distances. This ABSR-LIBS technique improved both the LIBS signal and the maximum emission intensity of Al atoms by several times at the best spatial position in our experimental conditions. Furthermore, we successfully obtained well-resolved line emission spectroscopy signals without any external time delay using a nongated spectrometer based on the ABSR-LIBS system. We consider that the ABSR-LIBS technique has great potential for obtaining new insights with laser-induced plasma instruments and it could facilitate the development of a low-cost instrument.
文摘An arc model considering deviations from thermodynamic and chemical equilibrium has been developed in order to achieve a better understanding of the arc plasma close to material surfaces.The model is based on unified consideration of the thermionic tungsten cathode,the arc region and the flat anode made of copper.The heat transfer within the electrodes is coupled with the plasma through the energy fluxes onto the electrode boundaries.Electrical characteristics of an 8 mm long free-burning arc are presented along with findings from spectroscopic measurements of the plasma emission in atmospheric pressure argon.The arc current varied from 60 A up to 200 A,and the gas flow rate was set at 12 L/min(at atmospheric pressure,room temperature).
