Heterogeneous interface engineering is closely related to the structural design of electromagnetic absorbers;thus,the interface control through structural design is a considerable approach to optimize the electromagne...Heterogeneous interface engineering is closely related to the structural design of electromagnetic absorbers;thus,the interface control through structural design is a considerable approach to optimize the electromagnetic wave absorption(EWA)performance.Herein,the 3D hierarchical structure composites composed of two-dimensional reduced graphite oxide(rGO)and hollow raspberry Fe_(3)O_(4) nanoparticles was successfully fabricated by a simple pyrolysis and self-assembly process.This specific structure enriches the characteristics of interface polarization and dipole polarization,which further induces significant EWA behavior.By adjusting the amount of graphite oxide(GO),the complex dielectric constant of the obtained hybrids can be controlled,and the heterointerface can be cleverly adjusted.The minimum reflection loss(RLmin)of the typical products can be up to−73.86 dB at the thickness is only 1.35 mm,and the maximum effective absorption bandwidth(EAB)can reach 5.1 GHz.This work demonstrates that the unique structure and tunable components can fully improve the potential of electromagnetic absorption performance,which provides basic guidance for the heterogeneous interface engineering of efficient electromagnetic functional materials.展开更多
Two three-dimensional supramolecular water architectures,[Zn(phen)3]2 ·[Zn(C10H16O4)·(H2O)3]·(C10H16O4)2·20H2O(1) and [Co(phen)3]2 ·[Co(H2O)6]·(C10H16O4)3·30H2O(2)[phen=1,10-Phenanth...Two three-dimensional supramolecular water architectures,[Zn(phen)3]2 ·[Zn(C10H16O4)·(H2O)3]·(C10H16O4)2·20H2O(1) and [Co(phen)3]2 ·[Co(H2O)6]·(C10H16O4)3·30H2O(2)[phen=1,10-Phenanthroline,C10H16O4=sebacic dianion],have been synthesized and characterized by IR,elemental analysis,thermogravimetric analysis,and single-crystal X-ray diffractions.The two structures both contain extensive hydrogen bonding between water molecules as well as between water molecules and sebacic anions.The water molecules and sebacic acid O atoms assembled 2D supramolecular corrugated sheets with different morphology in the two complexes.展开更多
基金support from the National Nature Science Foundation of China(Nos.51971111 and 52273247)the Fund of Prospective Layout of Scientific Research for NUAA(Nanjing University of Aeronautics and Astronautics(No.ILA220461A22).
文摘Heterogeneous interface engineering is closely related to the structural design of electromagnetic absorbers;thus,the interface control through structural design is a considerable approach to optimize the electromagnetic wave absorption(EWA)performance.Herein,the 3D hierarchical structure composites composed of two-dimensional reduced graphite oxide(rGO)and hollow raspberry Fe_(3)O_(4) nanoparticles was successfully fabricated by a simple pyrolysis and self-assembly process.This specific structure enriches the characteristics of interface polarization and dipole polarization,which further induces significant EWA behavior.By adjusting the amount of graphite oxide(GO),the complex dielectric constant of the obtained hybrids can be controlled,and the heterointerface can be cleverly adjusted.The minimum reflection loss(RLmin)of the typical products can be up to−73.86 dB at the thickness is only 1.35 mm,and the maximum effective absorption bandwidth(EAB)can reach 5.1 GHz.This work demonstrates that the unique structure and tunable components can fully improve the potential of electromagnetic absorption performance,which provides basic guidance for the heterogeneous interface engineering of efficient electromagnetic functional materials.
文摘Two three-dimensional supramolecular water architectures,[Zn(phen)3]2 ·[Zn(C10H16O4)·(H2O)3]·(C10H16O4)2·20H2O(1) and [Co(phen)3]2 ·[Co(H2O)6]·(C10H16O4)3·30H2O(2)[phen=1,10-Phenanthroline,C10H16O4=sebacic dianion],have been synthesized and characterized by IR,elemental analysis,thermogravimetric analysis,and single-crystal X-ray diffractions.The two structures both contain extensive hydrogen bonding between water molecules as well as between water molecules and sebacic anions.The water molecules and sebacic acid O atoms assembled 2D supramolecular corrugated sheets with different morphology in the two complexes.
