Bioactive calcium phosphate coatings were deposited by radio-frequency magnetron sputtering from biphasic targets of hydroxyapatite and tricalcium phosphate,sintered at different mass%ratios.According to Raman scatter...Bioactive calcium phosphate coatings were deposited by radio-frequency magnetron sputtering from biphasic targets of hydroxyapatite and tricalcium phosphate,sintered at different mass%ratios.According to Raman scattering and X-ray diffraction data,the deposited hydroxyapatite coatings have a disordered structure.High-temperature treatment of the coatings in air leads to a transformation of the quasi-amorphous structure into a crystalline one.A correlation has been observed between the increase in the Ca content in the coatings and a subsequent decrease in Ca in the biphasic targets after a series of deposition processes.It was proposed that the addition of tricalcium phosphate to the targets would led to a finer coating's surface topography with the average size of 78 nm for the structural elements.展开更多
This article gives a brief introduction to manufacturers and markets of sputtering targets as well as the manufacturing technology thereof. Then, it analyzes the application of high-purity gold sputtering targets in t...This article gives a brief introduction to manufacturers and markets of sputtering targets as well as the manufacturing technology thereof. Then, it analyzes the application of high-purity gold sputtering targets in the fields of integrated circuit, information storage, flat panel display, etc. Based on the above, the article analyzes the processing development trend for the high-purity gold sputtering targets in aspects of ultra-high purity, manufacturing technology, analysis and testing technologies.展开更多
对球磨时间不同的Cu2Se、In2Se3和Ga2Se3混合粉末进行热压烧结制备CIGS靶材,发现在球磨时间较短时靶材出现分层,随着球磨时间延长分层缺陷消失。由此考察了粉末在球磨过程中发生的物理化学变化及其对分层的影响。结果表明:Cu2Se、In2Se3...对球磨时间不同的Cu2Se、In2Se3和Ga2Se3混合粉末进行热压烧结制备CIGS靶材,发现在球磨时间较短时靶材出现分层,随着球磨时间延长分层缺陷消失。由此考察了粉末在球磨过程中发生的物理化学变化及其对分层的影响。结果表明:Cu2Se、In2Se3和Ga2Se3三种硒化物粉末在球磨过程中发生机械合金化反应形成黄铜矿相Cu(In,Ga)Se2(CIGS)。随着球磨时间的延长,黄铜矿相结构Cu In Se2(CIS)首先在Cu-Se二元化合物表面产生,并随着Ga原子的扩散逐步形成CIGS四元相。当球磨时间达到48 h时,粉末由黄铜矿相CIGS和少量Ga2Se3组成。由于Cu2-xSe与CIGS晶体结构相近,因此通过外延反应的方式有效促进了CIGS的合成。球磨过程中Cu-Se二元相的消失和CIGS相的形成有助于抑制烧结过程中分层缺陷的产生。展开更多
Iron nitride film is a qualifed material for high-density magnetic recording head for its excellent magnetic properties and good corrosion resistance. It is well known that there are four iron nitride phases, α″-Fe&...Iron nitride film is a qualifed material for high-density magnetic recording head for its excellent magnetic properties and good corrosion resistance. It is well known that there are four iron nitride phases, α″-Fe<sub>16</sub>N<sub>2</sub>, γ′-Fe<sub>4</sub>N, ε-Fe<sub>x</sub>N,（2【x≤3） and ζ-Fe<sub>2</sub>N. Their saturation magnetization （M<sub>s</sub>） and Curie temperature decrease with the increase of展开更多
Though the structure of α"-Fe<sub>16</sub>N<sub>2</sub> was well known, the great interest in Fe<sub>16</sub>N<sub>2</sub> arose from its giant saturation magnetic...Though the structure of α"-Fe<sub>16</sub>N<sub>2</sub> was well known, the great interest in Fe<sub>16</sub>N<sub>2</sub> arose from its giant saturation magnetic flux density which was found to be 2.58T at room temperature. The research work on preparing Fe<sub>16</sub>N<sub>2</sub> in high abundance is active on both bulk materials and thin film form. However, up to now, only Sugita and his coworkers have successfully prepared Fe<sub>16</sub>N<sub>2</sub> single-crystal films on semiconductor substrates because of its metastable property. They manifested that the M<sub>s</sub> was up to 2.9 T at展开更多
基金The study was conducted as part of the program of fundamental research of the state academies of sciences(PFR SAS)for 2015e2017 No.23.2.5The project was supported by Marie Curie IRSES,project No.612691 of the EU Framework Programme-FP7The authors thank A.Sainova,Yu.Glushko,M.Surmeneva,and Prof.M.Chaikina for support to the research and fruitful discussion of the results.
文摘Bioactive calcium phosphate coatings were deposited by radio-frequency magnetron sputtering from biphasic targets of hydroxyapatite and tricalcium phosphate,sintered at different mass%ratios.According to Raman scattering and X-ray diffraction data,the deposited hydroxyapatite coatings have a disordered structure.High-temperature treatment of the coatings in air leads to a transformation of the quasi-amorphous structure into a crystalline one.A correlation has been observed between the increase in the Ca content in the coatings and a subsequent decrease in Ca in the biphasic targets after a series of deposition processes.It was proposed that the addition of tricalcium phosphate to the targets would led to a finer coating's surface topography with the average size of 78 nm for the structural elements.
基金National key technology support program(2012BAE06B05)
文摘This article gives a brief introduction to manufacturers and markets of sputtering targets as well as the manufacturing technology thereof. Then, it analyzes the application of high-purity gold sputtering targets in the fields of integrated circuit, information storage, flat panel display, etc. Based on the above, the article analyzes the processing development trend for the high-purity gold sputtering targets in aspects of ultra-high purity, manufacturing technology, analysis and testing technologies.
文摘对球磨时间不同的Cu2Se、In2Se3和Ga2Se3混合粉末进行热压烧结制备CIGS靶材,发现在球磨时间较短时靶材出现分层,随着球磨时间延长分层缺陷消失。由此考察了粉末在球磨过程中发生的物理化学变化及其对分层的影响。结果表明:Cu2Se、In2Se3和Ga2Se3三种硒化物粉末在球磨过程中发生机械合金化反应形成黄铜矿相Cu(In,Ga)Se2(CIGS)。随着球磨时间的延长,黄铜矿相结构Cu In Se2(CIS)首先在Cu-Se二元化合物表面产生,并随着Ga原子的扩散逐步形成CIGS四元相。当球磨时间达到48 h时,粉末由黄铜矿相CIGS和少量Ga2Se3组成。由于Cu2-xSe与CIGS晶体结构相近,因此通过外延反应的方式有效促进了CIGS的合成。球磨过程中Cu-Se二元相的消失和CIGS相的形成有助于抑制烧结过程中分层缺陷的产生。
基金Project supported by the National Natural Science Foundation of China
文摘Iron nitride film is a qualifed material for high-density magnetic recording head for its excellent magnetic properties and good corrosion resistance. It is well known that there are four iron nitride phases, α″-Fe<sub>16</sub>N<sub>2</sub>, γ′-Fe<sub>4</sub>N, ε-Fe<sub>x</sub>N,（2【x≤3） and ζ-Fe<sub>2</sub>N. Their saturation magnetization （M<sub>s</sub>） and Curie temperature decrease with the increase of
基金the National Natural Science Foundation of China.
文摘Though the structure of α"-Fe<sub>16</sub>N<sub>2</sub> was well known, the great interest in Fe<sub>16</sub>N<sub>2</sub> arose from its giant saturation magnetic flux density which was found to be 2.58T at room temperature. The research work on preparing Fe<sub>16</sub>N<sub>2</sub> in high abundance is active on both bulk materials and thin film form. However, up to now, only Sugita and his coworkers have successfully prepared Fe<sub>16</sub>N<sub>2</sub> single-crystal films on semiconductor substrates because of its metastable property. They manifested that the M<sub>s</sub> was up to 2.9 T at
