膜分离技术在有机分子污水的处理中具有广泛应用,其面临的难题之一是制备具有超亲水性质的纳孔膜以抵御有机污染物的污染,实现高效、稳定的分子分离.在本文中,我们通过全膜交联的方法在保持水凝胶纳孔膜超亲水性质的前提下大幅提升了其...膜分离技术在有机分子污水的处理中具有广泛应用,其面临的难题之一是制备具有超亲水性质的纳孔膜以抵御有机污染物的污染,实现高效、稳定的分子分离.在本文中,我们通过全膜交联的方法在保持水凝胶纳孔膜超亲水性质的前提下大幅提升了其机械强度,制备了高强度超亲水纳孔膜.该膜实现了有机分子的高效分离,水通量达到220 L m^(-2)h^(-1)bar^(-1),考马斯亮蓝(CBB)截留率达到~99.9%,分子/盐(CBB/Na_(2)SO_(4))选择性达到747.在以腐殖酸为污染物的分子分离中,该膜表现出优异的抗污染性能,通量恢复率接近100%.该膜还具有出色的抗压性能,在高达8 bar的跨膜压力下保持了稳定的分子分离性能.本工作为制备超亲水纳孔膜实现有机分子废水的高效分离提供了一种新的思路.展开更多
Stabilization of tearing modes and neoclassical tearing modes is of great importance for tokamak operation.Electron cyclotron waves(ECWs)have been extensively used to stabilize the tearing modes with the virtue of hig...Stabilization of tearing modes and neoclassical tearing modes is of great importance for tokamak operation.Electron cyclotron waves(ECWs)have been extensively used to stabilize the tearing modes with the virtue of highly localized power deposition.Complete suppression of the m/n=2/1 tearing mode(TM)by electron cyclotron resonance heating(ECRH)has been achieved successfully on the J-TEXT tokamak.The effects of ECW deposition location and power amplitude on the 2/1 TM suppression have been investigated.It is found that the suppression is more effective when the ECW power is deposited closer to the rational surface.As the ECW power increases to approximately 230 k W,the 2/1 TM can be completely suppressed.The island rotation frequency is increased when the island width is reduced.The experimental results show that the local heating inside the magnetic island and the resulting temperature perturbation increase at the O-point of the island play dominant roles in TM suppression.As the ECW power increases,the 2/1 island is suppressed to smaller island width,and the flow shear also plays a stabilizing effect on small magnetic islands.With the stabilizing contribution of heating and flow shear,the 2/1 TM can be completely suppressed.展开更多
Grand canonical Monte Carlo simulation(GCMCs)is utilized for studying hydrogen storage gravimetric density by pha-graphene at different metal densities,temperatures and pressures.It is demonstrated that the optimum ad...Grand canonical Monte Carlo simulation(GCMCs)is utilized for studying hydrogen storage gravimetric density by pha-graphene at different metal densities,temperatures and pressures.It is demonstrated that the optimum adsorbent location for Li atoms is the center of the seven-membered ring of pha-graphene.The binding energy of Li-decorated phagraphene is larger than the cohesive energy of Li atoms,implying that Li can be distributed on the surface of pha-graphene without forming metal clusters.We fitted the force field parameters of Li and C atoms at different positions and performed GCMCs to study the absorption capacity of H_(2).The capacity of hydrogen storage was studied by the differing density of Li decoration.The maximum hydrogen storage capacity of 4Li-decorated pha-graphene was 15.88 wt%at 77 K and100 bar.The enthalpy values of adsorption at the three densities are in the ideal range of 15 kJ·mol^(-1)-25 kJ·mol^(-1).The GCMC results at different pressures and temperatures show that with the increase in Li decorative density,the hydrogen storage gravimetric ratio of pha-graphene decreases but can reach the 2025 US Department of Energy's standard(5.5 wt%).Therefore,pha-graphene is considered to be a potential hydrogen storage material.展开更多
The reservoir thickness of sub-member of Lower Permain in the south of the eastern margin of Ordos Basin is thin and large variable i laterally. And the seismic response characteristics of sandstone reservoir are doub...The reservoir thickness of sub-member of Lower Permain in the south of the eastern margin of Ordos Basin is thin and large variable i laterally. And the seismic response characteristics of sandstone reservoir are doubly interfered by the strong reflection sidelobes of overlying 5# coal seam and underlying 8# coal seam. In view of this situation, in order to better eliminate the influence of upper and lower coal seams and improve the accuracy of reservoir prediction, the strategy of de-strong seismic reflection and de-logging (curve) interference is adopted to carry out the matching of logging and seismic, and on this basis, uses the seismic waveform indication inversion to predict the thin sandstone. The steps are as follows: firstly, by using wavelet decomposition and reconstruction technology, select the seismic wavelet component that can better characterize the reservoir or oil & gas to reasonablely reconstruct seismic data, weaken the influence of the strong reflection from overlying 5# coal seam and underlying 8# coal seam, and highlight the response of weak seismic reflection of tight sandstone in Shan 2<sup>3</sup> sub-member;Then, the acoustic value of coal seam is corrected to that of mudstone on the logging curve to maintain the consistency of logseismic data. This method realizes the effective identification of sandstone reservoir in Shan 2<sup>3</sup> sub-member, and greatly improves the target-penetrated rate and sandstone-penetrated rate of horizontal wells.展开更多
基金financially supported by the National Key Research and Development Plan of China(2019YFA0705800)。
文摘膜分离技术在有机分子污水的处理中具有广泛应用,其面临的难题之一是制备具有超亲水性质的纳孔膜以抵御有机污染物的污染,实现高效、稳定的分子分离.在本文中,我们通过全膜交联的方法在保持水凝胶纳孔膜超亲水性质的前提下大幅提升了其机械强度,制备了高强度超亲水纳孔膜.该膜实现了有机分子的高效分离,水通量达到220 L m^(-2)h^(-1)bar^(-1),考马斯亮蓝(CBB)截留率达到~99.9%,分子/盐(CBB/Na_(2)SO_(4))选择性达到747.在以腐殖酸为污染物的分子分离中,该膜表现出优异的抗污染性能,通量恢复率接近100%.该膜还具有出色的抗压性能,在高达8 bar的跨膜压力下保持了稳定的分子分离性能.本工作为制备超亲水纳孔膜实现有机分子废水的高效分离提供了一种新的思路.
基金supported by the National Magnetic Confinement Fusion Energy R&D Program of China(No.2019YFE03010004)the Hubei Provincial Natural Science Foundation of China(No.2022CFA072)National Natural Science Foundation of China(No.51821005)。
文摘Stabilization of tearing modes and neoclassical tearing modes is of great importance for tokamak operation.Electron cyclotron waves(ECWs)have been extensively used to stabilize the tearing modes with the virtue of highly localized power deposition.Complete suppression of the m/n=2/1 tearing mode(TM)by electron cyclotron resonance heating(ECRH)has been achieved successfully on the J-TEXT tokamak.The effects of ECW deposition location and power amplitude on the 2/1 TM suppression have been investigated.It is found that the suppression is more effective when the ECW power is deposited closer to the rational surface.As the ECW power increases to approximately 230 k W,the 2/1 TM can be completely suppressed.The island rotation frequency is increased when the island width is reduced.The experimental results show that the local heating inside the magnetic island and the resulting temperature perturbation increase at the O-point of the island play dominant roles in TM suppression.As the ECW power increases,the 2/1 island is suppressed to smaller island width,and the flow shear also plays a stabilizing effect on small magnetic islands.With the stabilizing contribution of heating and flow shear,the 2/1 TM can be completely suppressed.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11904175,11804169,and 11804165)the Graduate Innovation Project of Jiangsu Province,China(Grant No.KYCX210700)。
文摘Grand canonical Monte Carlo simulation(GCMCs)is utilized for studying hydrogen storage gravimetric density by pha-graphene at different metal densities,temperatures and pressures.It is demonstrated that the optimum adsorbent location for Li atoms is the center of the seven-membered ring of pha-graphene.The binding energy of Li-decorated phagraphene is larger than the cohesive energy of Li atoms,implying that Li can be distributed on the surface of pha-graphene without forming metal clusters.We fitted the force field parameters of Li and C atoms at different positions and performed GCMCs to study the absorption capacity of H_(2).The capacity of hydrogen storage was studied by the differing density of Li decoration.The maximum hydrogen storage capacity of 4Li-decorated pha-graphene was 15.88 wt%at 77 K and100 bar.The enthalpy values of adsorption at the three densities are in the ideal range of 15 kJ·mol^(-1)-25 kJ·mol^(-1).The GCMC results at different pressures and temperatures show that with the increase in Li decorative density,the hydrogen storage gravimetric ratio of pha-graphene decreases but can reach the 2025 US Department of Energy's standard(5.5 wt%).Therefore,pha-graphene is considered to be a potential hydrogen storage material.
文摘The reservoir thickness of sub-member of Lower Permain in the south of the eastern margin of Ordos Basin is thin and large variable i laterally. And the seismic response characteristics of sandstone reservoir are doubly interfered by the strong reflection sidelobes of overlying 5# coal seam and underlying 8# coal seam. In view of this situation, in order to better eliminate the influence of upper and lower coal seams and improve the accuracy of reservoir prediction, the strategy of de-strong seismic reflection and de-logging (curve) interference is adopted to carry out the matching of logging and seismic, and on this basis, uses the seismic waveform indication inversion to predict the thin sandstone. The steps are as follows: firstly, by using wavelet decomposition and reconstruction technology, select the seismic wavelet component that can better characterize the reservoir or oil & gas to reasonablely reconstruct seismic data, weaken the influence of the strong reflection from overlying 5# coal seam and underlying 8# coal seam, and highlight the response of weak seismic reflection of tight sandstone in Shan 2<sup>3</sup> sub-member;Then, the acoustic value of coal seam is corrected to that of mudstone on the logging curve to maintain the consistency of logseismic data. This method realizes the effective identification of sandstone reservoir in Shan 2<sup>3</sup> sub-member, and greatly improves the target-penetrated rate and sandstone-penetrated rate of horizontal wells.
