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Conductivity Method as a New Monitoring Technique for Corrosion and Corrosion Inhibition Processes of Zinc Metal

Conductivity Method as a New Monitoring Technique for Corrosion and Corrosion Inhibition Processes of Zinc Metal
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摘要 The electrical conductivity method was successfully applied as a new monitoring technique to monitor the corrosion and corrosion inhibition processes of zinc metal. Measurements of electrical conductivity at 20.0°C of three different corrosive solutions (HCl, NaOH, and NaCl) were performed with two different concentrations (0.10 and 1.00 M) containing zinc sheets in the absence and presence of four different concentrations of sodium lignosulfonate (1.0, 5.0, 10.0, and 20.0 mM). The analysis of curves that illustrates the changes in electrical conductivity of these solutions provides qualitative information about the strength of corrosion as well as the extent of corrosion inhibition behavior. The results obtained from electrical conductivity measurements revealed that sodium lignosulfonate was an effective corrosion inhibitor in acidic medium (for both 0.10 and 1.00 M HCl) in which it converted into lignosulfonic acid, but was less effective in salt and alkaline media. The electrical conductivity method was successfully applied as a new monitoring technique to monitor the corrosion and corrosion inhibition processes of zinc metal. Measurements of electrical conductivity at 20.0°C of three different corrosive solutions (HCl, NaOH, and NaCl) were performed with two different concentrations (0.10 and 1.00 M) containing zinc sheets in the absence and presence of four different concentrations of sodium lignosulfonate (1.0, 5.0, 10.0, and 20.0 mM). The analysis of curves that illustrates the changes in electrical conductivity of these solutions provides qualitative information about the strength of corrosion as well as the extent of corrosion inhibition behavior. The results obtained from electrical conductivity measurements revealed that sodium lignosulfonate was an effective corrosion inhibitor in acidic medium (for both 0.10 and 1.00 M HCl) in which it converted into lignosulfonic acid, but was less effective in salt and alkaline media.
作者 Abdelmnim M. Altwaiq Sa’ib J. Khouri Rami A. Abdel-Rahem Ahmad K. Alkhawaldeh Abdelmnim M. Altwaiq;Sa’ib J. Khouri;Rami A. Abdel-Rahem;Ahmad K. Alkhawaldeh(Department of Chemistry, College of Arts and Sciences, University of Petra, Amman, Jordan;Department of Basic Sciences, American University of Madaba, Amman, Jordan;Department of Chemistry, The University of Jordan, Amman, Jordan)
出处 《American Journal of Analytical Chemistry》 2020年第10期349-361,共13页 美国分析化学(英文)
关键词 CONDUCTIVITY Monitoring Technique CORROSION Corrosion Inhibitor LIGNOSULFONATE Conductivity Monitoring Technique Corrosion Corrosion Inhibitor Lignosulfonate
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