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软硬酸碱理论在绿色缓蚀剂中的应用 被引量:5

The Application of the Principle of Hard and Soft Acids and Bases (HSAB) in the Field of Green Corrosion Inhibitor
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摘要 较系统地综述了软硬酸碱理论及其该理论在缓蚀剂研究领域中的应用。着重介绍了软硬酸碱理论与缓蚀效率的关系 ,软硬酸碱理论在选择局部腐蚀的铁的缓蚀剂和具有自修复能力的铜、铁、锌的绿色化学缓蚀剂中的应用 ,并侧重评述了对环境友好的具有自修复能力的“自组装层膜”的研究历史。 The hard and soft acids and bases theory (HSAB) and its application in the field of corrosion inhibitor were systemically reviewed in this paper. The relationship between the HSAB principle and corrosion inhibition efficiency was determined by the HSAB principle according to the corresponding electrochemical measurements (such as AC impedance, polarization method, etc.) The use of the HSAB theory in selecting the Green corrosion inhibitors with self-healing ability for Cu?Fe?Zn and the inhibitors for localized corrosion of Fe were particularly emphasized. The studying history, structure and mechanism of environmentally-friendly self-assembled layer were also discussed in the article.
出处 《辽宁化工》 CAS 2004年第2期103-107,共5页 Liaoning Chemical Industry
关键词 软硬酸碱理论 缓蚀剂 绿色化学 HSAB principle Corrosion inhibitor Green Chemistry Self-assembled layer
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