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新型锂离子电池正极材料LiMPO_4(M=Fe,Mn)的谱学和电化学研究 被引量:26

Spectroscopic and Electrochemical Studies on Novel Cathode Materials LiMPO_4 (M=Fe,Mn) for Lithium Ion Batteries
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摘要 采用固相反应与液相反应,合成了新型锂离子电池正极材料LiMPO4(M=Fe,Mn)。粉末X光衍射表明材料均为纯相。对材料的显微拉曼光谱和红外光谱进行了研究和指认。循环伏安研究表明,含锂磷酸盐是一类有潜力的锂离子电池正极材料。 A series of novel cathode materials for lithium ion batteries, Li-contained phosphates LiMPO_4 (M=Fe, Mn), were synthesized by solid state reaction or wet chemical method. Powder X-ray diffraction patterns indicate the as-prepared samples are all pure phases. Raman and FTIR spectroscopic studies of these materials were carried out and the vibrational bands were assigned. Cyclic voltammograms indicate that the Li-contained phosphates can serve as cathode materials for lithium ion batteries.
出处 《光散射学报》 2003年第4期231-236,共6页 The Journal of Light Scattering
关键词 锂离子电池 正极材料 拉曼光谱 红外光谱 含锂磷酸盐 可充电池 磷酸铁锂 磷酸锰锂 电化学 Lithium ion batteries cathode materials Li-contained phosphates spectroscopy Raman FTIR electrochemical properties
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