摘要
A series-of lanthanide complexes including (Ind)(3)Sm(THF) (1), [(MeCP)(2)Sm(mu-SPh)(THF)](2),(2), [(MeCp)(2)Y(mu-O-i-Pr)](2) (3), (MeCp)(3)Sm.THF (4), Sm(SPh)(3) (hmpa)(3) (5), [(MeCp)(2)Y(mu-OCH2CF3)](2) (6) and (CF3CH2O)(3)Y(THF)(3) (7) were synthesized and they have good activity for the oligomerization of phenyl isocyanate. Among-them 5 shows,the highest activity. The conversion is as high as 96.2%, with 1/2500 of the molar ratio of cat. / PhNCO. The main components in oligomer were characterized to be a cyclodimer and a cyclotrimer. The ratio of cyclodimer,to cyclotrimer depends on the lanthanide complexes:used. 7 gave 85.2% cyclotrimer with 1/300 of the molar ratio of cat./PhNCO at 40 V for 0.5 h, while 5 gave 77.6% cyclodimer with 1/300 of the molar ratio of cat. /PhNCO at 40 degreesC for 4 h.
A series-of lanthanide complexes including (Ind)(3)Sm(THF) (1), [(MeCP)(2)Sm(mu-SPh)(THF)](2),(2), [(MeCp)(2)Y(mu-O-i-Pr)](2) (3), (MeCp)(3)Sm.THF (4), Sm(SPh)(3) (hmpa)(3) (5), [(MeCp)(2)Y(mu-OCH2CF3)](2) (6) and (CF3CH2O)(3)Y(THF)(3) (7) were synthesized and they have good activity for the oligomerization of phenyl isocyanate. Among-them 5 shows,the highest activity. The conversion is as high as 96.2%, with 1/2500 of the molar ratio of cat. / PhNCO. The main components in oligomer were characterized to be a cyclodimer and a cyclotrimer. The ratio of cyclodimer,to cyclotrimer depends on the lanthanide complexes:used. 7 gave 85.2% cyclotrimer with 1/300 of the molar ratio of cat./PhNCO at 40 V for 0.5 h, while 5 gave 77.6% cyclodimer with 1/300 of the molar ratio of cat. /PhNCO at 40 degreesC for 4 h.
基金
ProjectsupportedbytheNationalNaturalScienceFoundationofChina (Nos .2 9872 0 3 1and 2 9672 0 2 6)
