摘要
以(Bu_4N)_4Mo_8O_(26)为原料,以邻巯基苯酚和苯甲酰肼为配体,在甲醇中合成了未见报道的单核三元配合物二邻巯基苯酚-苯甲酰肼合钼(Ⅳ)酸双三乙基亚铵.通过元素分析、红外光谱、~1H NMR谱、电子光谱、差热-热重分析对化合物的性质进行了表征,发现它是无端基氧钼配合物,并提出了其可能结构.
The ternary complex of monomolybdenum (Et3NH)2[(SC6H4O)2Mowas synthesized in methanol with o-mercaptophenol and benzoylhydrazine as the ligand and (Bu4N[MG9O26]as the parent The properties of the complex were characterized by elemental analysis,molar conductivity,electronic spectra,infrared spectra,1H NMR spectra and TG-DTA,The most possible structure is proposed on the basis of the spectral data and the IR spectra show that the complex has not terminal oxygen atoms,
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1992年第10期1197-1200,共4页
Chemical Journal of Chinese Universities
关键词
钼硫键
钼氮键
合成
钼络合物
Molybdenum complex,Molybdenum-Sulfur bond,Molybdenum-Nitrogen bond,Synthesis
