摘要
以（ｎ－Ｂｕ４Ｎ）４［ＭＯ８Ｏ２６］为原料、邻巯基苯酚为配体，在甲醇中合成了混合价多核钼配合物（ｎ－Ｂｕ４Ｎ）４［ＭＯ５Ｏ８］．通过元素分析、红外光谱、１ＨＮＭＲ谱、电子光谱、ＥＳＰ谱、差热－热重分析对此化合物进行了表征，并提出其可能结构．
The polymolybdenum complex(Bu.N).LMo,O,(SM),J was synthesized in methanol with o-mercaptophenol as the ligand and (Bu.N).[Mo8O26]as the parent.The properties of the complex were characterized by elemental analysis,molar conductivity,electronic spectra,infrared spectra. 1HNMR spectra and TG-DTA. The most possible structure is proposed on the basis of the spectra data.
出处
《广西师范大学学报（自然科学版）》
CAS
1994年第2期43-46,共4页
Journal of Guangxi Normal University:Natural Science Edition
关键词
钼硫键
钼络合物
邻硫基苯酚
polymolybdenum
complex
molybdemum-sulfur bond
