摘要
高分子科学和超分子化学的相互作用产生了多种多样的聚合物超分子体系,其可能具有丰富的超分子结构,并由此带来特殊的性质与功能.我国许多高校和科研院所自20世纪80年代开始从事聚合物超分子体系的研究,并在高分子自组装、超分子聚合以及功能超分子体系等研究方面取得了一系列重要创新成果.由于篇幅有限,此综述只选择介绍了几个代表性的研究实例,展示了如何从分子设计出发,发展和建立自组装的方法,将结构构筑与功能组装结合,构建多种多样的聚合物超分子体系的思想和成果.
The interplay between polymer science and supramolecular chemistry leads to formation of various polymeric supramolecular systems.Polymeric supramolecular systems may be of abundant supramolecular structures,thus endowed with many fascinating properties and functions such as reversibility,adaptiveness,selfhealing,and stimuli-responsiveness owing to the dynamic nature of noncovalent interactions.This review is aimed to summarize some research progresses on polymeric supramolecular systems in China,including mesogenjacketed liquid crystalline polymers,non-covalent connected micelles,supramolecular self-assemblies from amphiphilic hyperbranched polymers,layer-by-layer assemblies,supramolecular polymers from controllable fabrication,and artificial molecular chaperones from controllable assembly.
作者
张希
王力彦
徐江飞
陈道勇
史林启
周永丰
沈志豪
Xi Zhang;Li-yan Wang;Jiang-fei Xu;Dao-yong Chen;Lin-qi Shi;Yong-feng Zhou;Zhi-hao Shen(Department of Chemistry,Tsinghua University,Beijing100084;College of Chemistry,Jilin University,Changchun130012;Department of Macromolecular Science,Fudan University,Shanghai200438;Institute of Polymer Chemistry,College of Chemistry,Nankai University,Tianjin300071;School of Chemistry and Chemical Engineering,Shanghai Jiao Tong University,Shanghai200240;College of Chemistry and Molecular Engineering,Peking University,Beijing100871)
出处
《高分子学报》
SCIE
CAS
CSCD
北大核心
2019年第10期973-987,共15页
Acta Polymerica Sinica
关键词
高分子科学
超分子化学
分子自组装
功能组装体
Polymer science
Supramolecular chemistry
Self-assembly
Functional assembly
