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Synthesis,phase transformation and applications of CeCO_(3)OH:A review

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摘要 CeCO_(3)OH has a unique crystal structure and excellent optical,electronic and catalytic properties,which has been widely investigated for many applications.Interestingly,ceria obtained from CeCO_(3)OH has a morphology that is similar to that of the precursor,and the CeO_(2)-based products obtained from CeCO_(3)OH exhibit outstanding properties,such as catalytic performances,owing to their designed morphology and oxygen vacancies(OVs).To introduce CeCO_(3)OH into a wider range of potential researchers,we first systematically review the physico-chemical properties,synthesis,reaction and morphology tuning mechanism of CeCO_(3)OH,and summarize the conversion behavior from CeCO_(3)OH to ceria.Then,we thoroughly survey the applications of CeCO_(3)OH and its conversion products.Suggestions for further investigations of CeCO_(3)OH are also made in this review.It is hoped that the exhaustive co mpilation of the valuable properties and considerable potential investigations of CeCO_(3)OH will promote further applications of CeCO_(3)OH and CeO_(2)-based functional materials.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 2024年第8期1403-1420,I0001,共19页 稀土学报(英文版)
基金 supported by the National Natural Science Foundation of China (52164025) Basic Research Program from Science&Technology Department of Guizhou Province (20201Y219) Natural Science Research Project of Guizhou Provincial Department of Education (2022041)。
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