摘要
聚丙烯(PP)熔喷布表面自由电荷易在湿气等作用下流失,导致过滤层及口罩快速失效。针对以上问题,采用静电纺丝技术在PP熔喷布基体上制备压电聚(偏氟乙烯-三氟乙烯)(P(VDF-TrFE))纤维层,得到PP熔喷布/P(VDF-TrFE)改性过滤层。探究了纺丝工艺对压电纤维形貌和结构的影响,进一步分析了改性过滤层经过水洗、蒸汽等耐久性处理后的静电压、烟雾过滤效率和透气性的变化。结果表明:PP熔喷布/P(VDF-TrFE)改性过滤层对PM_(2.5)的过滤效率较PP熔喷布提高了25%,在进风量为85 L/min时的过滤效率提升了27.5%;经过2次水洗、紫外线照射、蒸煮消毒等方式处理后的改性过滤层,其表面电荷具有多次弯折后可再生的特点,过滤效率维持在90%,有效提高了口罩的防护效率和使用寿命,压电材料在外力作用下可产生束缚电荷,改善了过滤层负载电荷的稳定性,从而提升了口罩防护的长效性和安全性。
Objective Polypropylene(PP)melt-blown fabric has an electrically charged surface that generates an electrostatic field to adsorb micron-sized particles and is widely used as a filter layer in disposable protective masks.However,the free charge was found to be easily lost in the presence of moisture,leading to rapid failure of the filter layer and mask.Disposing of large numbers of masks also puts enormous pressure on environmental protection efforts.Therefore,there is an urgent need to develop masks with high protection capacity and long service life.Method A piezoelectric poly(vinylidene fluoride-trifluoroethylene)(P(VDF-TrFE))fiber layer was prepared by electrospinning on a PP melt-blown fabric substrate,resulting in a PP melt-blown fabric/P(VDFTrFE)modified filter layer.The modified filter layers took advantage of the fact that piezoelectric materials can generate a bound charge under external forces,providing the mask with a durable electrostatic adsorption capability.The influence of spinning process on the morphology and structure of piezoelectric fibers was studied,and the research further investigated the changes in static voltage,smoke filtration efficiency and breathability of the modified filter layer after durability treatment such as water washing and steam treatment.Results An optimized electrostatic spinning process was found to prepare excellent-performance piezoelectric P(VDF-TrFE)fiber membranes.The fibers prepared by spinning were free of beads and uniform diameter,with a distinct piezoelectric crystal phase structure,which ensures the breathability of the fiber membrane while providing the mask with a stable load of charge and a durable electrostatic adsorption capacity(Fig.2,Fig.3).The piezoelectric fiber layer showed a 25%higher filtration efficiency for PM_(2.5) than the ordinary PP melt-blown fabric in the smoke filtration effect test.In the standard test of medical masks,the filtration efficiency of the modified filter layer was improved by 10.5%and 27.5%at an inlet airflow of 32 and 85 L
作者
张晋
张林军
解云川
王健
贾寅峰
路涛
张志成
ZHANG Jin;ZHANG Linjun;XIE Yunchuan;WANG Jian;JIA Yinfeng;LU Tao;ZHANG Zhicheng(School of Chemistry,Xi′an Jiaotong University,Xi′an,Shaanxi 710049,China;Xi′an Modern Chemistry Research Institute,Xi′an,Shaanxi 710065,China;Xi′an Aerospace Composites Research Institute,Xi′an,Shaanxi 710025,China;Xi′an Bareno Electromechanical Technology Co.,Ltd.,Xi′an,Shaanxi 710025,China)
出处
《纺织学报》
EI
CAS
CSCD
北大核心
2023年第7期26-32,共7页
Journal of Textile Research
基金
山东省自然科学基金项目(ZR2020LFG010)
中央高校基本科研业务费专项资金资助项目(XZY032020017)
西安近代化学研究所开放合作创新基金项目(SYJJ20210421)。
关键词
聚(偏氟乙烯-三氟乙烯)
聚丙烯熔喷布
静电纺丝
压电材料
长效过滤防护
呼吸气阻
口罩
poly(vinylidene fluoride-trifluoroethylene)
polypropylene melt-blown fabric
electrospinning
piezoelectric material
long-lasting filterability
breathing resistance
mask
