摘要
To realize the commercialize of rechargeable Zn-air battery(RZAB),developing metal-free bifunctional electrocatalysts with satisfactory activity for oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)is one of the emerging issues.Herein,a prawn shells-derived N-enriched porous carbon(PSNC)is synthesized via an ion exchange coupled biomimetic selfsacrificing template strategy.The resulting PSNC displays unique functional components,including the interconnected macro-meso-micropores structure to shorten charge and mass transfer pathway,high content of pyridinic and graphitic nitrogen to construct rich catalytic active site and improve conductivity.As electrocatalysts in alkaline condition,the optimized PSNC-0.8 achieves excellent bifunctional catalytic propriety with a narrow potential gap(ΔE)value of 0.80 V.Meanwhile,PSNC-0.8-based RZAB displays a high peak power density of 176.5 mW·cm^(-2)and considerable cycling durability with a small battery efficiency delay of 6.5%after 480 cycles(320 h).This study enlightens a simple and effective conception to design high-performance metal-free bifunctional electrocatalysts from seafood waste.
出处
《Rare Metals》
SCIE
EI
CAS
CSCD
2023年第4期1186-1194,共9页
稀有金属（英文版）
基金
financially supported by the Innovative Youth Talents of Guangdong Education Department Support Program(No.2021KQNCX027)
the Youth Innovative Talents Project of Zhanjiang(No.2021E05016)
the Program forScientific Research Start-Up Funds of Guangdong Ocean University(Nos.060302122010 and R19047)。
