摘要
综述了具有安全性能高、储氢密度大和便于运输优点的金属氢化物储氢技术及其常用材料,主要包括综述镧系、钛系、镁系和锂系等不同金属储氢材料国内外应用现状;介绍了金属氢化物材料的储氢原理、容量和动力学行为,表明通过加入适当的催化剂以及通过引入具有改善的表面性质的缺陷的球磨,可以提高材料动力学性质和循环寿命。提出通过改善金属氢化物的热行为和循环行为,研发具有竞争性的高容量储氢材料。
The present review reports the metal hydride hydrogen storage technology and its commonly used materials,which have the advantages of high safety performance,high hydrogen storage density and convenient transportation.It includes recent developments of different metal hydrogen storage materials such as lanthanide,titanium,magnesium and lithium.The researches introduced the hydrogen storage principle,capacity and kinetic behavior of metal hydride materials,and showed that by adding appropriate catalysts and by introducing ball milling with defects with improved surface properties,material dynamics and cycle life can be improved.It is proposed to develop competitive high-capacity hydrogen storage materials by improving the thermal behavior and cycling behavior of metal hydrides.
作者
高媛
禹国军
张利智
黄德家
GAO Yuan;YU Guo-jun;ZHANG Li-zhi;HUANG De-jia(Merchant Marine College,Shanghai Maritime University,Shanghai 201306,China;UL-CCIC Company Limited,Suzhou 215127,China)
出处
《应用化工》
CAS
CSCD
北大核心
2022年第10期2975-2978,2984,共5页
Applied Chemical Industry
基金
国家自然基金(51606117)
上海市自然科学基金项目(20ZR1423300)。
关键词
氢能源
固态储氢
金属氢化物
储氢原理
hydrogen energy
solid state hydrogen storage
metal hydrides
principle of hydrogen storage
