摘要
5-羟甲基糠醛(5-hydroxymethylfurfural,5-HMF)又称5-羟甲基-2-糠醛,是一种呋喃类化合物,与焦糖化反应、美拉德反应密切相关,化学性质较为活泼。5-HMF广泛存在于乳制品、焦糖化食品中,对食品的颜色和风味有一定的影响,可作为反映食品新鲜及褐变程度的指示物。5-HMF在体外和体内通过磺基转移酶(sulfotransferase,SULT)会转化为5-磺氧基甲基糠醛(5-sulfooxymethylfurfural,5-SMF),对皮肤黏膜、眼睛等产生刺激,还会损伤人体的骨骼肌、肾脏等器官。但随着深入研究,5-HMF的抗氧化性、抗菌性等生物活性也逐渐被人们所发现。根据5-HMF目前在食品中的研究现状,其通用脱除和检测手段较少,本文综述了5-HMF的产生过程及理化性质,阐述了5-HMF的生物活性以及在食品中的应用,以期为改善含5-HMF食品的品质、探索5-HMF的通用检测及弱化方法奠定理论基础。
5-hydroxymethylfurfural(5-HMF),also known as 5-hydroxymethyl-2-furfural,is a furan compound,which is closely related to caramelization and Maillard reaction,and has relatively active chemical properties.5-HMF widely exists in dairy products and caramelized foods,which has a certain influence on the color and flavor of food,and can be used as an indicator to reflect the freshness and browning degree of food.5-HMF can be converted into 5-sulfooxymethylfurfural(5-SMF)by sulfotransferase(SULT)in vitro and in vivo,which can stimulate skin mucosa,eyes and damage skeletal muscle,kidney and other organs of human body.But with the further study,5-HMF’s antioxidant,antibacterial and other biological activities have been gradually discovered.According to the current research status of 5-HMF in food,there are few common methods for its removal and detection.This paper reviewed the production process and physicochemical properties of 5-HMF,and described the biological activity and application of 5-HMF in food,in order to improve the quality of food containing 5-HMF,explore 5-HMF general detection and weakening methods to lay a theoretical foundation.
作者
朱秀清
雷文华
黄雨洋
刘琳琳
朱颖
ZHU Xiu-Qing;LEI Wen-Hua;HUANG Yu-Yang;LIU Lin-Lin;ZHU Ying(Key Laboratory of Grain Food and Comprehensive Processing of Grain Resource of Heilongjiang Province,College of Food Engineering,Harbin University of Commerce,Harbin 150028,China)
出处
《食品安全质量检测学报》
CAS
北大核心
2022年第15期4983-4991,共9页
Journal of Food Safety and Quality
基金
黑龙江省“百千万”工程科技重大专项支撑行动计划项目(2021ZX12B04)
黑龙江省“百千万”工程科技重大专项(2019ZX08B01-04)
黑龙江省自然科学基金重点项目(ZD2019C005)
黑龙江省自然科学基金联合引导项目(LH2020C060)。
关键词
5-羟甲基糠醛
安全性
理化性质
5-hydroxymethylfurfural
security
physicochemical property
