摘要
Molybdenum disulfide(MoS_(2)),a typical two-dimensional transition metallic layered material,attracts tremendous attentions in the electrochemical energy storage due to its excellent physicochemical properties.However,with the deepening of the research and exploration of the lithium storage mechanism of these advanced MoS_(2)-based anode materials,the complex reaction process influenced by internal and external factors hinders the exhaustive understanding of the lithium storage process.To design stable anode material with high performance,it is urgent to review the mechanisms of reported anode materials and summarize the related factors that influence the reaction processes.This review aims to dissect all possible side reactions during charging and discharging process,uncover internal and external factors inducing various anode reactions and finally put forward strategies of controlling high cycling capacity and super-stable lithium storage capability of MoS_(2).This review will be helpful to the design of MoS_(2)-based lithium-ion batteries(LIBs) with excellent cycle performance to enlarge the application fields of these advanced electrochemical energy storage devices.
基金
financially supported by the National Funds for Distinguished Young Scientists (No. 61825503)
the National Natural Science Foundation of China (Nos. 51902101, 61775101,61804082)
the Youth Natural Science Foundation of Hunan Province (No. 2019JJ50044)
Natural Science Foundation of Jiangsu Province (No. BK20201381)
Science Foundation of Nanjing University of Posts and Telecommunications (No. NY219144)
China Postdoctoral Science Foundation (Nos. 2020TQ0202, 2021M692161)。
