期刊文献+

磁性金属有机框架复合材料在生物分析中的应用 被引量:1

Application of magnetic metal organic framework composites in bioanalysis
原文传递
导出
摘要 金属-有机框架(MOFs)是由金属离子或团簇和有机配体,通过配位键自行组装形成的具有多孔结构的有机-无机杂化材料。由于它们具有框架结构可调、高孔隙率、化学稳定性良好、可再生性和合成过程简单等优点而广泛应用于小分子的吸附分离、催化化学反应、催化降解、富集物质、氧化还原反应等诸多领域。磁性金属有机框架(MMOFs)是在金属有机框架的基础上引进磁性金属粒子,极大地改良并优化了其原有的性能,丰富了金属有机框架的研究内容,拓宽了金属有机框架在食品、农药、生物分析中的应用。本文以磁性金属有机框架为研究对象,对其在生物分析中的应用进行了系统论述,在此基础上总结了当前MMOFs材料在该领域中存在的局限,并对研究新趋向提出了展望。 Metal-organic framework(MOFs)was an organic-inorganic hybrid material with porous structure formed by self-assembly of metal ions or clusters and organic ligands through coordination bonds.They have the advantages of adjustable frame structure,high porosity,good chemical stability,reproducibility and simple synthesis process.Therefore,it was widely used in adsorption and separation of small molecules,catalytic chemical reaction,catalytic degradation,enrichment of substances,REDOX reaction,drug dilution and other fields.Magnetic metal organic framework(MMOFs)introduces magnetic metal particles on the basis of metal organic framework,greatly improves and optimizes its original performance,enriches the research content of metal organic framework,and widens the application of metal organic framework in food,pesticide and biology analysis.In this paper,the application of magnetic metal-organic framework in bioanalysis was systematically discussed.On this basis,the limitations of current MMOFs materials in this field were summarized,and the new trend of research was proposed.
作者 关桦楠 彭勃 薛悦 吴巧艳 张悦 GUAN Hua'nan;PENG Bo;XUE Yue;WU Qiaoyan;ZHANG Yue(College of Food Engineering,Harbin University of Commerce,Harbin 150028,China)
出处 《复合材料学报》 EI CAS CSCD 北大核心 2022年第4期1547-1558,共12页 Acta Materiae Compositae Sinica
基金 国家自然科学基金(31871747,31201376,31370649) 黑龙江省自然科学基金(C2016034) 黑龙江省普通本科高等学校青年创新人新才培养计划(UNPYSCT-2016060) 中国博士后基金(2014T70304 2013M531009) 黑龙江省博士后资助项目(LBH-Z13002) 哈尔滨商业大学科研项目(17XN026) 哈尔滨商业大学大学生创新创业训练计划项目(201810240080)。
关键词 磁性纳米粒子 金属有机框架 食品分析 模拟酶 富集 magnetic nanoparticle metal-organic frameworks food analysis mimetic enzyme enrichmen
  • 相关文献

参考文献8

二级参考文献78

  • 1Wu CD,Hu A,Zhang L,Lin WB.A homochiral porous metal- organic framework for highly enantioselective heterogeneous asymme- tric catalysis. Journal of the American Chemical Society . 2005 被引量:1
  • 2Lee S,Mallik AB,Xu Z,Lobkovsky EB,Tran L.Small amphiphilic organics,coordinated extended solids,and constant curvature struc- tures. Accounts of Chemical Research . 2005 被引量:1
  • 3Suslick KS,Bhyrappa P,Chou JH,Kosal ME,Nakagaki S,Smithen- ry DW,Wilson SR.Microporous porphyrin solids. Accounts of Chemical Research . 2005 被引量:1
  • 4Dinc M,Long JR.High-enthalpy hydrogen adsorption in cation- exchanged variants of the microporous metal-organic framework Mn3[ (Mn4Cl)3 (BTT)8 (CH3OH)10]2. Journal of the American Chemical Society . 2007 被引量:1
  • 5Zhao JA,Mi LW,Hu JY,Hou HW,Fan YT.Cation exchange in- duced tunable properties of a nanoporous octanuclear Cu (II) wheel with double helical structure. Journal of the American Chemical Society . 2008 被引量:1
  • 6Kuppler RJ,Timmons DJ,Fang QR,Li JR,Makal TA,Young MD,Yuan DQ,Zhao D,Zhuang WJ,Zhou HC.Potential applications of metal-organic frameworks. Coordination Chemistry Reviews . 2009 被引量:1
  • 7Meek ST,Greathouse JA,Allendorf MD.Metal-organic frameworks: A rapidly growing class of versatile nanoporous materials. Advanced Materials . 2011 被引量:1
  • 8Kahn O.Molecular Maleculor. . 1993 被引量:1
  • 9Gatteschi D,Sessoli R,Villain J.Molecular Nanomagnets. . 2006 被引量:1
  • 10Perry IV JJ,Perman JA,Zaworotko MJ.Design and synthesis of metal-organic frameworks using metal-organic polyhedra as super- molecular building blocks. Chemical Society Reviews . 2009 被引量:1

共引文献38

同被引文献13

引证文献1

二级引证文献3

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部