摘要
Under solvothermal condition,the reaction of furan-2,5-dicaboxylate(H2FDA) and glycol with Gd(NO3)3.6H2O gave microporous lanthanide metal-organic framework(MOF),{[Gd(FDA)1.5(glycol)].1.5H2O}}n(1).This compound was characterized by single crystal X-ray diffraction,infrared spectroscopy,elemental analysis,thermogravimetry analysis,and powder X-ray diffraction.The Gd(III) ions were connected by carboxylic group of FDA2-to give 1D chains,which were further linked by FDA2-,forming a 3D porous framework with 3D channels.Gas adsorption properties with N2,H2 and CO_(2) of the compound were studied.Magnetic studies show that there are weak ferromagnetic interactions transmitted by μ1,3 carboxylic group between the Gd(III) ions.
Under solvothermal condition,the reaction of furan-2,5-dicaboxylate(H2FDA) and glycol with Gd(NO3)3.6H2O gave microporous lanthanide metal-organic framework(MOF),{[Gd(FDA)1.5(glycol)].1.5H2O}}n(1).This compound was characterized by single crystal X-ray diffraction,infrared spectroscopy,elemental analysis,thermogravimetry analysis,and powder X-ray diffraction.The Gd(III) ions were connected by carboxylic group of FDA2-to give 1D chains,which were further linked by FDA2-,forming a 3D porous framework with 3D channels.Gas adsorption properties with N2,H2 and CO_(2) of the compound were studied.Magnetic studies show that there are weak ferromagnetic interactions transmitted by μ1,3 carboxylic group between the Gd(III) ions.
基金
supported by grants from the National Natural Science Foundation of China(90922032 & 20801028)
the Natural Science Foundation of Tianjin(09JCZDJC22100 and 09JCYBJC04000)
Specialized Research Fund for the Doctoral Program of Higher Education of China(20100031110009 & IRT0927)
