摘要
The transformation of carbon dioxide(CO_(2))into fuels and chemicals is an interesting topic,which has been paid much attention in recent years.The materials with specific functionalities are highly required for CO_(2)capture and conversion,which have been widely investigated.As an emerging material platform,porous organic polymers(POPs)have attracted considerable scientific interest due to their distinctive properties such as tailorable func-tionalization,large surface areas,adjustable porosity,versatile polymerizations,good physicochemical and thermal stability.Our group focuses on designing and synthesizing POPs via introducing CO_(2)-philic groups and organic ligands into the skeletons of the polymers and immobilizing metal active species onto their surface,and a series of POPs with functional groups,such as,azo,Tr€oger's base,fluorine,phenolic–OH,have been prepared for CO_(2)transformation.In this review article,we mainly introduce our recent work on design of POPs-based catalysts for CO_(2)transformation,which include POPs-based catalysts for cycloaddition reactions of epoxides and prop-argylic alcohols with CO_(2),for reductive transformation of CO_(2)with H 2,for photocatalytic/electrocatalytic reduction of CO_(2).In addition,the perspectives of the POP-based catalysts for CO_(2)transformation will be discussed as well.
基金
The authors thank the National Natural Science Foundation of China(22121002,21773266)
Chinese Academy of Sciences(121111KYSB20200057)for the financial support.
