摘要
高功率快放型锂离子电池是目前锂离子电池领域研究的重点方向之一.为了获得具有高功率密度的锂离子电池,正极材料须具有较高的电压和较高的电子与离子导电率,正极材料主要包括高电压钴酸锂、镍锰酸锂和高电压三元材料,负极材料包括碳系材料、钛基材料和金属氧化物材料,以及为提高首效和降低负极电位而采用的预嵌锂方法,并对锂离子电池电解液用锂盐、溶剂和添加剂进行了综述.最终总结了功率密度测试方法,并对高功率锂离子电池的研究进行展望.
High-power and fast-discharging lithium-ion battery,which can be used in smart power grids,rail transits,electromagnetic launch systems,aerospace systems,and so on,is one of the key research directions in the field of lithium-ion batteries and has attracted increasing attention in recent years.To obtain lithium-ion batteries with a high power density,the cathode materials should possess high voltage and high electronic/ionic conductivity,which can be realized by selecting high-voltage materials and modifying them to improve the voltage and reduce the battery’s internal resistance.Currently,the cathode materials of high-power lithium-ion batteries mainly include high-voltage LiCoO2,LiNi0.5Mn1.5O4,and Li(NiCoMn)O2 materials.Meanwhile,the anode materials include carbon-and Ti-based materials and metal oxides.This paper reviews the research on the modification of these materials,such as element doping and surface coating,which have gained considerable attention nowadays,as well as some new types of anode materials that exhibit excellent electrochemical properties.In terms of the negative electrode,the prelithiation process is one of the effective means to improve the power performance of a lithium-ion battery.This process’s significance is to compensate the consumption of Li+and reduce the potential of the negative electrode to the working range for improving the platform voltage of the battery and improving the power density and energy density.This paper summarizes several commonly used prelithiation methods of the lithium-ion battery.Finally,the lithium salts,solvents,and additives for the electrolytes of lithium-ion batteries are introduced on the basis of their classification,properties,and performances.Several new types of lithium salts and additives are mentioned herein,such as lithium bis(fluorosulfonyl)imide,lithium bis(oxalate)borate,and tetramethylene sulfone.Furthermore,this paper summarizes several common power density test methods of lithium-ion batteries and prospects the research of high-power lith
作者
陈港欣
孙现众
张熊
王凯
马衍伟
CHEN Gang-xin;SUN Xian-zhong;ZHANG Xiong;WANG Kai;MA Yan-wei(Institute of Electrical Engineering,Chinese Academy of Sciences,Beijing 100190,China;University of Chinese Academy of Sciences,Beijing 100049,China;Institute of Electrical Engineering and Advanced Electromagnetic Drive Technology,Qilu Zhongke,Jinan 250013,China)
出处
《工程科学学报》
EI
CSCD
北大核心
2022年第4期612-624,共13页
Chinese Journal of Engineering
基金
国家自然科学基金资助项目(52077207,51907193)
北京市自然科学基金资助项目(JQ19012)。
关键词
高功率锂离子电池
正极材料
负极材料
电解液
预嵌锂
功率密度
high-power lithium-ion batteries
cathode materials
anode materials
electrolytes
prelithiation
power density
