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Tricarboxy Ligand CuⅡ Metal-organic Framework with Magnetic and Proton Conduction Properties

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摘要 Hydrothermal reaction of Cu(NO3)2·3 H2O and 4-(4-carboxyphenoxy)isophthalic acid(H3cpia)results in a two-dimensional coordination polymer based on paddle-wheel-like dinuclear clusters,namely[C60H54Cu4O39]n(1).Complex 1 is of triclinic system,space group P1 with a=10.7318(18),b=12.267(2),c=14.528(2)?,α=113.560(2)o,β=96.156(3)o,γ=103.552(3)o,V=1660.5(5)?3,Z=1,S=1.057,F(000)=842,R=0.0517 and wR=0.1426(I>2σ(I)).In this structure,tricarboxylate liagnds are partial deprotonation and potenial proton carriers.Strong antiferromagnetic interaction between CuⅡions exists within the Cu2 cluster and complex 1 exhibits relatively high proton conductivity(σ>1.23×10-5 S×cm-1)at 76%relative humidity(RH).
作者 SHEN Zhi LUO Bao-Min XIE Hai-Quan ZHAO Qiang 沈芝;罗保民;谢海泉;赵强(College of Chemistry and Pharmaceutical Engineering,Nanyang Normal University,Nanyang 473061,China)
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2020年第9期1689-1693,1556,共6页 结构化学(英文)
基金 supported by University Key Scientific Research Project of Henan Province(19B150014)。
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  • 1Long, J. R.; Yaghi, 0 ‘ M. The pervasive chemistry of metal-organic frameworks. Chem. Soc. Rev. 2009, 38,1213-1214. 被引量:1
  • 2Yaghi, O. M.; O'Keeffe, M.; Ockwig, N. W.; Chae, H. K.; Hddaoudi, M.; Kim, J. Reticular synthesis and thedesign of new materials. Nature 2003,423, 705-715. 被引量:1
  • 3Wu, H.; Yang, J.; Su, Z. M.; Batten, S. R.; Ma, J. F. An exceptional 54-fold interpenetrated coordination polymer with 103-SRS network topology. J.Am. Chem. Soc. 2011, 133, 11406-11409. 被引量:1
  • 4Train, C.; Nuida, T.; Gheorghe, R.; Gruselle, M.; Ohkoshi, S. Large magnetization induced second harmonic generation in an enantiopure chiralmagnet. J. Am. Chem. Soc. 2009, 131, 16838-16843. 被引量:1
  • 5Chen, B. L.; Xiang, S. G.; Qian, G. D. Metal-organic frameworks with functional pores for recognitionof small molecules. Acc. Chem. Res. 2010, 43, 1115-1124. 被引量:1
  • 6D'Alessandro, D. M.; Smit, B.; Long, J. R. Carbon dioxide capture: prospects for new materials. Angew. Chem. Int. Ed. 2010,49, 6058-6082. 被引量:1
  • 7Ye, Q.; Song, Y. M.; Wang, G. X.; Chen, K.; Fu, D. W.; Chan, P. W, H.; Zhu, J. S.; Huang, S. D. Ferroelectric metal-organic framework with a highdielectric constant. J. Am. Chem. Soc. 2006, 128, 6554-6555. 被引量:1
  • 8Li, Y.; Xu, G.; Zou, W. Q.; Wang, M. S.; Zheng, F. K.; Wu, M. F.; Zeng, H. Y.; Guo, G. C.; Huang, J. S. A novel metal organic network with highthermal stability: nonlinear optical and photoluminescent properties. Inorg. Chem. 2008,47,7945-7947. 被引量:1
  • 9Seo, J. S.; Whang, D.; Lee, H.; Jun, S. 1.; Oh, J.; Jeon, Y. J.; Kim, K. A homochiral metal-organic porous material for enantioselective separationand catalysis. Nature 2000,404, 982-986. 被引量:1
  • 10Heo, J.; Jeon, Y. M.; Mirkin, C. A. Reversible interconversion of homochiral triangular macrocycles and helical coordination polymers. J. Am.Chem. Soc. 2007, 129, 7712-7713. 被引量:1

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