摘要
To improve the proton conduction of crystalline porous organic salts(CPOS-l),H2SO4 and H3PO4 were introduced into the channel to obtain H2SO4@CPOS-1 and H3PO4@CPOS-1.Compared to CPOS-1,the proton conductivities of H2SO4@CPOS-1 and H3PO4@CPOS-1 increased two orders of magnitude and one order of magnitude at 303 K and 100%RH,respectively.It can be attributed to the increasing concentration of the protons,which disso ciates trom the acids.
基金
Supported by the National Natural Science Foundation of China(Nos.91956108,21871103)
the"111"Project,China(No.BP0719036)
the Foundation of the Science and Technology Department of Jilin Province,China(No.20180414009GH).